Home
Class 12
CHEMISTRY
Consider the following processes :- {:...

Consider the following processes :-
`{:(,DeltaH(kJ//mol)),((1)/(2)A rarr B,+150),(3B rarr2C+D,-125),(E+A rarr 2D,+350),("For "B+D rarr E+2C",",Delta H" will be"):}`

A

325 kJ / mol

B

525 kJ / mol

C

`-175` kJ / mol

D

`-325` kJ / mol

Text Solution

AI Generated Solution

The correct Answer is:
To find the value of ΔH for the reaction \( B + D \rightarrow E + 2C \), we will manipulate the given reactions and their associated enthalpy changes (ΔH). ### Given Reactions: 1. \( \frac{1}{2}A \rightarrow B \) (ΔH = +150 kJ/mol) 2. \( 3B \rightarrow 2C + D \) (ΔH = -125 kJ/mol) 3. \( E + A \rightarrow 2D \) (ΔH = +350 kJ/mol) ### Step-by-step Solution: **Step 1: Adjust the first reaction to isolate B.** - We need B on the left side for our target reaction. We can multiply the first reaction by 2 to get: \[ A \rightarrow 2B \quad (\Delta H = 2 \times 150 = +300 \text{ kJ/mol}) \] **Step 2: Adjust the second reaction.** - The second reaction already has B on the left side, but we need to reverse it to get B on the left side: \[ 2C + D \rightarrow 3B \quad (\Delta H = +125 \text{ kJ/mol}) \] **Step 3: Combine the adjusted first and second reactions.** - Now we combine the adjusted first reaction and the reversed second reaction: \[ A + 2C + D \rightarrow 2B + 3B \] - This simplifies to: \[ A + 2C + D \rightarrow 5B \quad (\Delta H = +300 + 125 = +425 \text{ kJ/mol}) \] **Step 4: Adjust the third reaction.** - We need to isolate A and D, so we can reverse the third reaction: \[ 2D \rightarrow E + A \quad (\Delta H = -350 \text{ kJ/mol}) \] **Step 5: Combine the reactions to form the target reaction.** - Now we combine the results from Steps 3 and 4: \[ A + 2C + D + 2D \rightarrow 5B + E + A \] - This simplifies to: \[ B + D \rightarrow E + 2C \quad (\Delta H = 425 - 350 = +75 \text{ kJ/mol}) \] ### Final Calculation of ΔH: - Thus, the ΔH for the reaction \( B + D \rightarrow E + 2C \) is: \[ \Delta H = +75 \text{ kJ/mol} \] ### Conclusion: The value of ΔH for the reaction \( B + D \rightarrow E + 2C \) is +75 kJ/mol. ---

To find the value of ΔH for the reaction \( B + D \rightarrow E + 2C \), we will manipulate the given reactions and their associated enthalpy changes (ΔH). ### Given Reactions: 1. \( \frac{1}{2}A \rightarrow B \) (ΔH = +150 kJ/mol) 2. \( 3B \rightarrow 2C + D \) (ΔH = -125 kJ/mol) 3. \( E + A \rightarrow 2D \) (ΔH = +350 kJ/mol) ### Step-by-step Solution: ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    ALLEN|Exercise EXERCISE -1B|22 Videos
  • THERMODYNAMICS

    ALLEN|Exercise EXERCISE -2|100 Videos
  • THERMODYNAMICS

    ALLEN|Exercise Questions|46 Videos
  • TEST PAPERS

    ALLEN|Exercise CHEMISTRY|19 Videos
  • Thermodynamics And Thermo Chemistry

    ALLEN|Exercise All Questions|39 Videos

Similar Questions

Explore conceptually related problems

Consider the following process :- Ato2B,DeltaH=+150 KJ 3Bto2C+D,DeltaH=+350 KJ G+Ato2D,DeltaH=+350 KJ For B+DtoG+2C,DeltaH will be

Consider the following equations for a cell reaction, A + B rarr C + D , E^(@) = x "volt", Delta G= Delta G_(1) 2A + 2B rarr 2C + 2D, E^(@) = y "volt", DeltaG = DeltaG_(2) Then,

The enthalpy change for the following process are listed below : (a) Cl_(2(g)) rarr 2Cl_((g)), DeltaH=242.3kJ mol^(-1) (b) I_(2(g))rarr 2I_((g)), DeltaH=151.0kJ mol^(-1) (c) ICl_((g)) rarr I_((g))+Cl_((g)), DeltaH=211.3kJ mol^(-1) (d) I_(2(s)) rarr I_(2(g)), DeltaH=62.76kJ mol^(-1) If standard state of iodine and chloride are I_(2(s)) and Cl_(2(g)) , the standard enthalpy of formation for ICl_((g)) is :

Complete the following reactions (a) XeF_(4) + H_(2)O rarr (b) XeF_(6) + SiO_(2) rarr (c ) XeF_(6) + H_(2) rarr (d) XeF_(6) + H_(2)O rarr (e ) XeF_(6) + SbF_(5) rarr (f) XeF_(6) + NH_(3) rarr

The conversion A to B is carried out by the following path : {:(C rarr D),(uarr" "darr),("A B"):} Given : Delta S_((A rarr C))=50 e.u. , Delta S_((C rarr D))=30 e.u., Delta S_((B rarr D))=20 e.u. where w.u. is entropy unit then Delta S_((A rarr B)) is

ALLEN-THERMODYNAMICS -EXERCISE -1A
  1. Standard entropy of X(2) , Y(2) and XY(3) are 60, 40 and 50JK^(-1)mol...

    Text Solution

    |

  2. Intensive property is :-

    Text Solution

    |

  3. In which of following there is decrease in entropy :-

    Text Solution

    |

  4. Which of the following is not a state function :-

    Text Solution

    |

  5. If the enthaply change for the transition of liquid water to steam is...

    Text Solution

    |

  6. Enthalpy change for the reaction, 4H((g))rarr 2H(2(g)) is -869.6 kJ ...

    Text Solution

    |

  7. Which of the following is the correct option for the free expansion of...

    Text Solution

    |

  8. Consider the following processes :- {:(,DeltaH(kJ//mol)),((1)/(2)A r...

    Text Solution

    |

  9. The enthalpy of formation of CO(g), CO(2)(g),N(2)O(g) and N(2)O(4)(g) ...

    Text Solution

    |

  10. For adiabatic process which is correct -

    Text Solution

    |

  11. Which of the following is not thermodynamic function -

    Text Solution

    |

  12. Which of the following is intensive property -

    Text Solution

    |

  13. In which of the following reactions,standard reaction entropy change(D...

    Text Solution

    |

  14. Standard enthalpy of vaporisationDeltaV(vap).H^(Theta) for water at 10...

    Text Solution

    |

  15. The enthalpy of funsion of water is 1.435 kcal/mol. The molar entropy ...

    Text Solution

    |

  16. The Gibbs energy for the decomposition of Al(2)O(3) at 500^(@)C is as ...

    Text Solution

    |

  17. At equilibrium which is correct :-

    Text Solution

    |

  18. Bond dissociation energy of CH(4) si 360 kJ/mol and C(2)H(6) has 620 k...

    Text Solution

    |

  19. Which of the following is true for ideal solution :-

    Text Solution

    |

  20. Which thermodynamic parameter is not a state function :-

    Text Solution

    |