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Enthalpy of 1 mole monoatomic ideal gas ...

Enthalpy of 1 mole monoatomic ideal gas is equals to :-

A

`(3)/(2)RT`

B

`(5)/(2)RT`

C

RT

D

2 RT

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The correct Answer is:
To find the enthalpy of 1 mole of a monoatomic ideal gas, we can follow these steps: ### Step 1: Understand the definition of enthalpy Enthalpy (H) is defined as: \[ H = U + PV \] where \(U\) is the internal energy, \(P\) is the pressure, and \(V\) is the volume. ### Step 2: Express internal energy for an ideal gas For an ideal gas, the internal energy \(U\) can be expressed as: \[ U = n C_v \Delta T \] where \(n\) is the number of moles, \(C_v\) is the molar heat capacity at constant volume, and \(\Delta T\) is the change in temperature. ### Step 3: Express the PV term The term \(PV\) can be expressed using the ideal gas law: \[ PV = nRT \] where \(R\) is the universal gas constant and \(T\) is the temperature. ### Step 4: Combine the expressions for enthalpy Substituting the expressions for \(U\) and \(PV\) into the enthalpy equation gives: \[ H = n C_v \Delta T + n R \Delta T \] Factoring out \(n \Delta T\) gives: \[ H = n (C_v + R) \Delta T \] ### Step 5: Relate \(C_p\) and \(C_v\) For an ideal gas, the relationship between \(C_p\) (molar heat capacity at constant pressure) and \(C_v\) is given by: \[ C_p = C_v + R \] Thus, we can rewrite the enthalpy equation as: \[ H = n C_p \Delta T \] ### Step 6: Substitute values for a monoatomic ideal gas For a monoatomic ideal gas, it is known that: \[ \frac{C_p}{C_v} = \frac{5}{3} \] From this, we can express \(C_v\) in terms of \(C_p\): \[ C_v = \frac{3}{5} C_p \] ### Step 7: Substitute \(C_v\) into the equation Using the relation \(C_p - C_v = R\): \[ C_p - \frac{3}{5} C_p = R \] This simplifies to: \[ \frac{2}{5} C_p = R \quad \Rightarrow \quad C_p = \frac{5}{2} R \] ### Step 8: Substitute \(C_p\) back into the enthalpy equation Now substituting \(C_p\) back into the enthalpy equation: \[ H = n \left(\frac{5}{2} R\right) \Delta T \] For 1 mole of gas (\(n = 1\)): \[ H = \frac{5}{2} R \Delta T \] ### Step 9: Final expression for enthalpy Thus, the enthalpy of 1 mole of a monoatomic ideal gas is: \[ H = \frac{5}{2} R T \] ### Final Answer The enthalpy of 1 mole of a monoatomic ideal gas is: \[ \frac{5}{2} R T \]

To find the enthalpy of 1 mole of a monoatomic ideal gas, we can follow these steps: ### Step 1: Understand the definition of enthalpy Enthalpy (H) is defined as: \[ H = U + PV \] where \(U\) is the internal energy, \(P\) is the pressure, and \(V\) is the volume. ...
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ALLEN-THERMODYNAMICS -EXERCISE -2
  1. q=-w is not true for :-

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  2. The temperature of an ideal gas increases in an:

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  3. Enthalpy of 1 mole monoatomic ideal gas is equals to :-

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  4. Which statement is true for reversible process :-

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  5. Both q & w are function & q + w is a function :-

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  6. If work done by the system is 300 joule when 100 cal. Heat is supplied...

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  7. A system has internal energy equal to U(1), 450J of heat is taken out ...

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  8. The work done by a system is 8J, when 40J heat is supplied to it. Calc...

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  9. If a gas absorbs 200J of heat and expands by 500 cm^(3) against a cons...

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  10. Identify the state quantiy among the following

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  11. Internal enregy change during a reversible is isothermal expansion of ...

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  12. Under which of the following conditions is the relation, Delta H = Del...

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  13. The difference heats of reaction at constant pressure and constant vol...

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  14. For a gaseous reaction, A(g)+3B(g)to3C(g)+3D(g),DeltaU is 17 kcal at 2...

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  15. For the reaction CO(g)+(1)/(2)O(2)(g)rarr CO(2)(g) Which one of the ...

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  16. For the reaction Ag(2)O(s)rarr 2Ag(s)+1//2O(2)(g), which one of the fo...

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  17. A mixture of 2 moles of carbon monoxide and one mole of oxygen in a cl...

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  18. For the gaseous reaction involving the complete combustion of iso-buta...

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  19. For the reversible isothermal expansion of one mole of an ideal gas at...

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  20. For CaCO(3)(s)rarr CaO(s)+CO(2)(g) at 977^(@)C, Delta H = 174 KJ/mol ,...

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