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In a spontaneous irreversible process th...

In a spontaneous irreversible process the total entropy of the system and surroundings

A

Remains constant

B

Increases

C

Decreases

D

Zero

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To solve the question regarding the total entropy of the system and surroundings in a spontaneous irreversible process, we can follow these steps: ### Step 1: Understand the Second Law of Thermodynamics The Second Law of Thermodynamics states that the total entropy of an isolated system can never decrease over time. In any spontaneous process, the total entropy will either remain constant (in the case of a reversible process) or increase (in the case of an irreversible process). **Hint:** Remember that the Second Law of Thermodynamics is fundamental in determining the behavior of entropy in different types of processes. ### Step 2: Differentiate Between Reversible and Irreversible Processes In a reversible process, the system is in equilibrium, and the total entropy change is zero. However, in an irreversible process, the system is not in equilibrium, and the entropy of the system and surroundings increases. **Hint:** Focus on the definitions of reversible and irreversible processes to understand how they affect entropy. ### Step 3: Apply the Concept to Spontaneous Irreversible Processes For spontaneous irreversible processes, the entropy of the system and surroundings increases. This increase in entropy reflects the natural tendency of systems to evolve towards a state of greater disorder or randomness. **Hint:** Think about how spontaneous processes tend to move towards more probable configurations, which corresponds to higher entropy. ### Step 4: Conclude the Effect on Total Entropy Since we are discussing a spontaneous irreversible process, we conclude that the total entropy of the system and surroundings increases. Therefore, the correct answer to the question is that the total entropy increases. **Hint:** Remember that the key takeaway for spontaneous irreversible processes is the increase in total entropy. ### Final Answer: In a spontaneous irreversible process, the total entropy of the system and surroundings increases.
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ALLEN-THERMODYNAMICS -EXERCISE -2
  1. Calculate the enthalpy of vaporisation per mole for ethanol. Given Del...

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  2. 5 mol of an ideal gas expand reversibly from a volume of 8 dm^(3) to 8...

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  3. In a spontaneous irreversible process the total entropy of the system ...

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  4. The total entropy change for a system and its surroundings increases, ...

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  5. Calculate the entropy of Br(2)(g) in the reaction H(2)(g)+Br(2)(g)rarr...

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  6. Ammonium chloride when dissolved in water leads to a cooling sensation...

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  7. In which of the following cases entropy decreases?

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  8. Which of the following state function is not zero at standard state :-

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  9. Entropy change for an adiabatic reversible process is

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  10. A gas is allowed to expand reversibly under adiabatic conditions. What...

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  11. For a reaction at 25^(@)C enthalpy change (Delta H) and entropy change...

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  12. The spontaneous nature of a reaction is impossible if :

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  13. At a certain temperature T, the endothermic reaction A rarr B proceeds...

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  14. If Delta H gt 0 and Delta S gt 0, the reaction proceeds spontaneously ...

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  15. The temperature at which the reaction : Ag(2)O(s)rarr 2Ag(s)+1//2O(2)(...

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  16. The enthalpy change for a given reaction at 298 K is -x cal mol^(-1). ...

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  17. Which of the following is true fo the reacion H(2)O(l)hArr H(2)O(g) at...

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  18. For the reaction Ag(2)O(s)rarr 2Ag(s)+1//2O(2)(g) the value of Delta H...

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  19. For hypothetical reversible reaction 1//2A(2)(g) +3//2B(2)(g) rarr A...

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  20. For the precipitation of AgCl by Ag^(+) ions and HCl

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