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How do we differentiate between Fe^(3+) ...

How do we differentiate between `Fe^(3+)` and `Cr^(3+)` in group III ?

A

By adding excess of `NH_(4)OH`

B

by increasing `NH_(4)^(+)` ions concentration

C

by decreaseing `OH^(-)` ion concentration

D

Both (b) and (C)

Text Solution

Verified by Experts

`OH^(-)` ions precipitates both `Fe^(3+)` and `Cr^(3+)` as their hydroxides. However, `Cr(OH)_(3)` is soluble in excess of `NH_(4)OH`
`Fe^(3+) +3OH^(-) to Fe(OH)_(3) darr`
`Cr^(3+) +3OH^(-) to Cr(OH)_(3) darr`
`Cr(OH)_(3)(s) +6NH_(3) (aq) to [Cr(NH_(3))_(6)](OH)_(3) (aq)`
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