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Show that the first few frequencies of l...

Show that the first few frequencies of light that are emitted when electrons falls to the nth level form levels higher than n, are approximate harmonics (i.e., in the ratio 1 : 2: 3...) when `n gt gt 1`.

Text Solution

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According to Bohr.s formula , the frequency of electromagnetic radiation emitted when electron falls from `p^(th)` level to the `n^(th)` level (p > n) is given by
`v_"pn"=cRZ^2[1/(n+k)^2-1/n^2]`
where p=n+k and k=1,2,3,….
R is the Rydberg.s constant
Z is the atomic number of atom
As k < < n,
`v_"pn"=cRZ^2[1/n^2(1+k/n)^(-2)-1/n^2]`
`=cRZ^2[1/n^2(1-(2k)/n)-1/n^2]`
`=cRZ^2[1/n^2 -(2k)/n^3-1/n^2]`
`=cRZ^2(2k)/n^3=((2cRZ^2)/n^3)k`
Since k=1,2,3,..., therefore , `v_"pn"` are approximate harmonics in the ratio 1:2:3....
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