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The number of 90^(@) bond angles present...

The number of `90^(@)` bond angles present in `SF_(4)` molecules is

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To determine the number of `90°` bond angles present in the `SF₄` molecule, we need to analyze its molecular structure and hybridization. ### Step-by-Step Solution: 1. **Identify the Valence Electrons:** - Sulfur (S) has an atomic number of 16. The electronic configuration is `1s² 2s² 2p⁶ 3s² 3p⁴`. - The valence electrons for sulfur are in the 3s and 3p orbitals. Sulfur has 6 valence electrons (2 from 3s and 4 from 3p). 2. **Determine the Hybridization:** - The formula for hybridization is given by: \[ \text{Hybridization} = \frac{1}{2} \left( \text{Valence Electrons} + \text{Monovalent Atoms} \right) \] - For `SF₄`, there are 4 fluorine atoms (which are monovalent). - Thus, the calculation is: \[ \text{Hybridization} = \frac{1}{2} \left( 6 + 4 \right) = \frac{10}{2} = 5 \] - This indicates that the hybridization of sulfur in `SF₄` is `sp³d`. 3. **Analyze the Molecular Geometry:** - The `sp³d` hybridization corresponds to a trigonal bipyramidal geometry. - In this geometry, there are 5 positions: 3 equatorial and 2 axial. 4. **Identify Lone Pairs and Bond Pairs:** - In `SF₄`, there are 4 bond pairs (from the 4 fluorine atoms) and 1 lone pair on sulfur. - The presence of the lone pair affects the geometry, leading to a seesaw shape. 5. **Determine Bond Angles:** - In a seesaw geometry, the bond angles are not all equal. - The equatorial bond angles are approximately `120°`, and the axial-equatorial bond angles are less than `90°` due to the lone pair's repulsion. 6. **Count the `90°` Bond Angles:** - In the seesaw structure of `SF₄`, there are no `90°` bond angles present. The angles between the axial and equatorial bonds are less than `90°` due to the lone pair's influence. ### Conclusion: The number of `90°` bond angles present in `SF₄` is **0**.

To determine the number of `90°` bond angles present in the `SF₄` molecule, we need to analyze its molecular structure and hybridization. ### Step-by-Step Solution: 1. **Identify the Valence Electrons:** - Sulfur (S) has an atomic number of 16. The electronic configuration is `1s² 2s² 2p⁶ 3s² 3p⁴`. - The valence electrons for sulfur are in the 3s and 3p orbitals. Sulfur has 6 valence electrons (2 from 3s and 4 from 3p). ...
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