Home
Class 11
CHEMISTRY
At 800 K, the equilibrium constant for t...

At 800 K, the equilibrium constant for the reaction,
`N_2(g) + 3H_2(g) hArr 2NH_3(g)` is `6.05xx10^(-2)L^2 "mol"^(-2)`. Calculate `K_p` for the reaction at the same temperature.

Text Solution

AI Generated Solution

The correct Answer is:
To calculate \( K_p \) for the reaction \( N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g) \) at 800 K, given that \( K_c = 6.05 \times 10^{-2} \, L^2 \, mol^{-2} \), we can use the relationship between \( K_p \) and \( K_c \): ### Step 1: Write the relationship between \( K_p \) and \( K_c \) The relationship is given by the equation: \[ K_p = K_c \cdot (R \cdot T)^{\Delta n_g} \] where: - \( R \) is the universal gas constant (0.0821 L·atm/(K·mol)), - \( T \) is the temperature in Kelvin, - \( \Delta n_g \) is the change in the number of moles of gas. ### Step 2: Calculate \( \Delta n_g \) For the reaction: - Reactants: \( N_2(g) + 3H_2(g) \) → Total moles = 1 + 3 = 4 moles - Products: \( 2NH_3(g) \) → Total moles = 2 moles Now, calculate \( \Delta n_g \): \[ \Delta n_g = \text{moles of products} - \text{moles of reactants} = 2 - 4 = -2 \] ### Step 3: Substitute the values into the equation Now we can substitute \( K_c \), \( R \), \( T \), and \( \Delta n_g \) into the equation: \[ K_p = K_c \cdot (R \cdot T)^{\Delta n_g} \] Substituting the values: - \( K_c = 6.05 \times 10^{-2} \, L^2 \, mol^{-2} \) - \( R = 0.0821 \, L \cdot atm/(K \cdot mol) \) - \( T = 800 \, K \) - \( \Delta n_g = -2 \) Calculating \( R \cdot T \): \[ R \cdot T = 0.0821 \cdot 800 = 65.68 \, L \cdot atm/mol \] Now, substitute into the equation: \[ K_p = 6.05 \times 10^{-2} \cdot (65.68)^{-2} \] ### Step 4: Calculate \( K_p \) Calculating \( (65.68)^{-2} \): \[ (65.68)^{-2} = \frac{1}{65.68^2} \approx 0.000230 \] Now substituting back: \[ K_p = 6.05 \times 10^{-2} \cdot 0.000230 \approx 1.39 \times 10^{-5} \, atm^{-2} \] ### Final Answer: \[ K_p \approx 1.39 \times 10^{-5} \, atm^{-2} \]

To calculate \( K_p \) for the reaction \( N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g) \) at 800 K, given that \( K_c = 6.05 \times 10^{-2} \, L^2 \, mol^{-2} \), we can use the relationship between \( K_p \) and \( K_c \): ### Step 1: Write the relationship between \( K_p \) and \( K_c \) The relationship is given by the equation: \[ K_p = K_c \cdot (R \cdot T)^{\Delta n_g} \] ...
Promotional Banner

Topper's Solved these Questions

  • EQUILIBRIUM

    MODERN PUBLICATION|Exercise Conceptual Question 1|24 Videos
  • EQUILIBRIUM

    MODERN PUBLICATION|Exercise Conceptual Question 2|15 Videos
  • EQUILIBRIUM

    MODERN PUBLICATION|Exercise Unit Practice Test|13 Videos
  • ENVIRONMENTAL POLLUTION

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|15 Videos
  • HALOALKANES AND HALOARENES

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|12 Videos

Similar Questions

Explore conceptually related problems

At 773 K, the equilibrium constant K_(c) for the reaction, N_(2) (g) + 3 H_(2) (g) hArr 2 NH_(3) (g)" is " 6.02 xx 10^(-2)L^(2) mol^(-2). Calculate the value of K_(p) at the same temperature.

At 500^(@)C the equilibrium constant for the reaction N_(2)(g) + 3H_(2) (g) hArr 2NH_(3)(g) is 6.02 xx 10^(-2) litre^(-2) mol^(-2) What is the value of K_(p) at the same temperature?

At 700 K , the equilibrium constant , K_p for the reaction 2SO_3(g) hArr 2SO_2(g) +O_2 (g) is 1.8 xx10^(-3) atm. The value of K_c for the above reaction at the same temperature in moles per litre would be

The equilibrium constant K_(p) for the reaction H_(2)(g)+I_(2)(g) hArr 2HI(g) changes if:

The value of K_p for the reaction at 500 K: 2NOCl(g) hArr 2NO(g)+Cl_2(g) is 1.8xx10^(-2) "bar"^(-1) . Calculate K_c for reaction at this temperature.

K_p is how many times equal to K_c for the given reaction ? N_2(g) +3H_2 (g) hArr 2NH_3(g)

A mixture of 1.57 mol of N_(2), 1.92 mol of H_(2) and 8.13 mol of NH_(3) is introduced into a 20 L reaction vessel at 500 K . At this temperature, the equilibrium constant K_(c ) for the reaction N_(2)(g)+3H_(2)(g) hArr 2NH_(3)(g) is 1.7xx10^(2) . Is the reaction mixture at equilibrium? If not, what is the direction of the net reaction?

The equilibrium constant for the reaction : N_2(g)+3H_2(g) hArr 2NH_3(g) at 715 K is 6.0xx10^(-2) If in a particular reaction , there are 0.25 mol L^(-1) of H_2 and 0.06 mol L^(-1) of NH_3 present at equilibrium , calculate the concentration of N_2 at equilibrium.

The equilibrium constant for the reaction N_2(g)+O_2(g) hArr 2NO(g) at temperature T is 4xx10^(-4) .The value of K_C for the reaction, NO(g) hArr 1/2 N_2(g)+1/2O_2(g) at the same temperature is :

MODERN PUBLICATION-EQUILIBRIUM-Practice Problems
  1. Write the relationship between Kp and Kc for the reaction 2SO2(g) +...

    Text Solution

    |

  2. Kp for the reaction : N2O4(g) hArr 2NO2(g) is 0.157 atm at 27^@C an...

    Text Solution

    |

  3. At 800 K, the equilibrium constant for the reaction, N2(g) + 3H2(g) ...

    Text Solution

    |

  4. Write the expression for equilibrium constant, K for each of the follo...

    Text Solution

    |

  5. Write the equilibrium constant expressions for the following reactions...

    Text Solution

    |

  6. The equilibrium constant for the reaction I2(g) +Cl2(g) hArr 2ICl(g)...

    Text Solution

    |

  7. For the reactions, N(2(g))+3H(2(g))hArr2NH(3(g)). At 400 K, K(p)=41 at...

    Text Solution

    |

  8. The value of Kp for the reaction at 500 K: 2NOCl(g) hArr 2NO(g)+Cl2(...

    Text Solution

    |

  9. For the reaction 2A(g)+2B2(g) hArr 2AB2(g) the equilibrium constan...

    Text Solution

    |

  10. Write the relationship between equilibrium constants for the following...

    Text Solution

    |

  11. The equilibrium constant for the reaction: 2SO2(g) +O2(g) hArr 2SO3(g...

    Text Solution

    |

  12. If 1 mole of acetic acid and 1 mole of ethyl alcohol are mixed togethe...

    Text Solution

    |

  13. Two moles of HI when heated at 444^@C until equilibrium is reached wer...

    Text Solution

    |

  14. One mole each of hydrogen and iodine are allowed to react at certain t...

    Text Solution

    |

  15. Equilibrium constant, K(c) for the reaction, N(2(g))+3H(2(g))hArr2NH...

    Text Solution

    |

  16. For the reaction: CH4(g)+2H2S(g) hArr CS2(g) + 4H2(g) at 1173 K, Kc=...

    Text Solution

    |

  17. At a certain temperature, equilibrium constant (Kc) is 16 for the reac...

    Text Solution

    |

  18. 1.5 mol of PCl(5) are heated at constant temperature in a closed vesse...

    Text Solution

    |

  19. For the reaction at 127^@ C N2(g) + 3H2(g) hArr 2NH3(g) the partia...

    Text Solution

    |

  20. The equilibrium constant K(p) of the reaction: 2SO(2)+O(2) hArr 2SO(3)...

    Text Solution

    |