Home
Class 11
CHEMISTRY
Calculate pH at which Mg(OH)(2) begins t...

Calculate pH at which `Mg(OH)_(2)` begins to precipitate from a solution containing `0.10M Mg^(2+)` ions. `(K_(SP)of Mg(OH)_(2)=1xx10^(-11))`

Text Solution

Verified by Experts

`[Mg^(2+)]=0.1 M, K_(sp)=1.0xx10^(-11)`
`Mg(OH)_2 hArr Mg^(2+) + 2OH^(-)`
`K_(sp)=[Mg^(2+)][OH^-]^2`
`1.0xx10^(-11)=(0.1)[OH^-]^2`
or `[OH^-]^2=(1.0xx10^(-11))/0.1=10^(-10),[OH^-]=10^(-5)` M
Now, `[H_3O^+][OH^-]=K_w=10^(-14)`
`[H_3O^+]=10^(-14)/([OH^-])=10^(-14)/10^(-5)=10^(-9)` M
pH=-log `[H_3O^+]=-log (10^(-9))` =9
Promotional Banner

Topper's Solved these Questions

  • EQUILIBRIUM

    MODERN PUBLICATION|Exercise NCERT File (Textbook Exercise)|72 Videos
  • EQUILIBRIUM

    MODERN PUBLICATION|Exercise NCERT File ( Exemplar Problems MCQ-I)|21 Videos
  • EQUILIBRIUM

    MODERN PUBLICATION|Exercise Conceptual Question 3|10 Videos
  • ENVIRONMENTAL POLLUTION

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|15 Videos
  • HALOALKANES AND HALOARENES

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|12 Videos

Similar Questions

Explore conceptually related problems

a. Will a precipitate of Mg(OH)_(2) be formed in a 0.001M solution of Mg(NO_(3))_(2) if the pH of solution is adjusted to 9.K_(sp) of Mg(OH)_(2) = 8.9 xx 10^(-12) . b. Calculate pH at which Mg(OH)_(2) begin to precipitae form a solution containing 0.1M Mg^(2+) ions. K_(sp) of Mg(OH)_(2) =1 xx 10^(-11) . c. Calculate [overset(Theta)OH] of a solution after 100mL of 0.1M MgC1_(2) is added to 100mL of 0.2M NaOH. K_(sp) Mg(OH)_(2) = 1.2 xx 10^(-11) .

What is the pH value at which Mg(OH)_(2) begins to precipitate from a solution containing 0.2 M Mg^(+2) ions ? K_(SP) of Mg(OH)_(2) is 2 xx 10^(-13) M^(2) ?

Calculate pH of a saturated solution of Mg(OH)_(2) . (K_(SP)for Mg(OH)_(2)=8.9xx10^(-12))

Should Mg(OH)_(2) precipitate from a solution that is 0.01 M MgCl_(2) if the solution is also made 0.10 M in NH_(3)[K_((sp)[Mg(OH)_(2)])=1.8 xx10^(-11) , K_(b(NH_(4)OH))= 1.8 xx 10^(-5)]

Calculate [overset(o+)NH_(4)] (derived from NH_(4)C1) needed to prevent Mg(OH)_(2) from precipitating is 1.0L of solution which contins 0.01mol NH_(3) and 0.001 mol Mg^(2+). K_(sp) Mg(OH)_(2) = 1.2 xx 10^(-11), K_(b) NH_(3) = 1.8 xx 10^(-5) .

A solution has 0.05M Mg^(2+) and 0.05M NH_(3) . Calculate the concentration of NH_(4)CI required to prevent the formation of Mg(Oh)_(2) in solution. K_(SP) for Mg(OH)_(2)=9.0xx10^(-12) and ionisation constant of NH_(3) is 1.8xx10^(-5) .

MODERN PUBLICATION-EQUILIBRIUM-Problems (Advanced Level)
  1. An equilibrium mixture at 300 K contains N(2)O(4) and NO(2) at 0.28 an...

    Text Solution

    |

  2. When 3.06 g of solid NH(4)HS is introduced into a two-litre evacuated ...

    Text Solution

    |

  3. At 817^(@)C, K(p) for the reaction between CO(2(g)) and excess hot gra...

    Text Solution

    |

  4. Ammonium carbamate (NH2COONH4) decomposes as: NH2COONH4(s) hArr 2NH...

    Text Solution

    |

  5. A mixture of SO(3), SO(2) and O(2) gases is maintained in a 10 L flask...

    Text Solution

    |

  6. The equilibrium constant of the reaction A(2)(g)+B(2)(g) hArr 2AB(g)...

    Text Solution

    |

  7. At 800K, Kp for the reaction: N2O4 hArr 2NO2 is 700 mm. Calculate ...

    Text Solution

    |

  8. The solubility of a salt of weak acid (AB) at pH 3 is Y xx 10^(-3) "...

    Text Solution

    |

  9. What is the pH of 1 M solution of acetic acid ? To what volume one lit...

    Text Solution

    |

  10. The pH of a solution of B(OH)2 is 10.6. Calculate its solubility and s...

    Text Solution

    |

  11. A sample of AgCI was treated with 5.00mL of 1.5M Na(2)CO(3) solubility...

    Text Solution

    |

  12. An acid type indicator, H In differs in colour from its conjugate base...

    Text Solution

    |

  13. Calculate pH at which Mg(OH)(2) begins to precipitate from a solution ...

    Text Solution

    |

  14. Two buffer, (X) and (Y) of pH 4.0 and 6.0 respectively are prepared fr...

    Text Solution

    |

  15. How many times of the acetic acid concentration, acetate salt should b...

    Text Solution

    |

  16. 50mL of a solution containing 10^(-3) mole of Ag^(+) is mixed with 5...

    Text Solution

    |

  17. What will be the resultant pH when 200 mL of an aqueous solution of HC...

    Text Solution

    |