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At equilibrium rate of forward reaction ...

At equilibrium rate of forward reaction becomes equal to rate of backward reaction.

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To solve the question, let's break down the concept of equilibrium in chemical reactions step by step. ### Step-by-Step Solution: 1. **Understanding Chemical Reactions**: - In a chemical reaction, reactants are converted into products. For example, consider a reversible reaction: \[ A + B \rightleftharpoons C + D \] 2. **Forward and Backward Reactions**: - The forward reaction is when reactants \( A \) and \( B \) are converted into products \( C \) and \( D \). - The backward reaction is when products \( C \) and \( D \) are converted back into reactants \( A \) and \( B \). 3. **Rate of Reactions**: - The rate of a reaction is a measure of how quickly reactants are converted to products. - The rate of the forward reaction can be expressed as \( \text{Rate}_{\text{forward}} = k_f [A][B] \), where \( k_f \) is the rate constant for the forward reaction. - The rate of the backward reaction can be expressed as \( \text{Rate}_{\text{backward}} = k_b [C][D] \), where \( k_b \) is the rate constant for the backward reaction. 4. **Equilibrium Condition**: - At equilibrium, the rates of the forward and backward reactions become equal: \[ \text{Rate}_{\text{forward}} = \text{Rate}_{\text{backward}} \] - This means that the concentration of reactants and products remains constant over time, even though both reactions are still occurring. 5. **Concentration at Equilibrium**: - At equilibrium, the concentrations of reactants \( [A] \) and \( [B] \) and products \( [C] \) and \( [D] \) do not change. This is because the rate at which \( A \) and \( B \) are converted into \( C \) and \( D \) is exactly balanced by the rate at which \( C \) and \( D \) are converted back into \( A \) and \( B \). 6. **Conclusion**: - Therefore, the statement "At equilibrium, the rate of forward reaction becomes equal to the rate of backward reaction" is true because the system has reached a state where the concentrations of reactants and products remain constant, indicating a dynamic balance between the forward and backward processes.
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