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Assertion : For a gaseous reaction : 2B ...

Assertion : For a gaseous reaction : 2B `to` A , the equilibrium constant `K_p` is less than `K_c`.
Reason: `K_p` is related to `K_c` as `K_p=K_c(RT)^(Deltan_g)`

A

Assertion and reason both are correct statements and Reason is correct explanation for assertion.

B

Assertion and reason both are correct statement but reason is not correct explanation for assertion

C

Assertion is correct statement but reason is wrong statement.

D

Assertion is wrong statement but reason is correct statement

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will analyze the assertion and the reason provided regarding the relationship between the equilibrium constants \( K_p \) and \( K_c \) for the reaction \( 2B \rightleftharpoons A \). ### Step-by-step Solution: 1. **Identify the Reaction and Variables**: The given reaction is: \[ 2B \rightleftharpoons A \] Here, we have 2 moles of gas \( B \) on the reactant side and 1 mole of gas \( A \) on the product side. 2. **Calculate \( \Delta n_g \)**: \( \Delta n_g \) is defined as the change in the number of moles of gas, calculated as: \[ \Delta n_g = \text{(moles of gaseous products)} - \text{(moles of gaseous reactants)} \] For our reaction: - Moles of gaseous products = 1 (from \( A \)) - Moles of gaseous reactants = 2 (from \( 2B \)) Thus, \[ \Delta n_g = 1 - 2 = -1 \] 3. **Relate \( K_p \) and \( K_c \)**: The relationship between \( K_p \) and \( K_c \) is given by the formula: \[ K_p = K_c (RT)^{\Delta n_g} \] Substituting \( \Delta n_g = -1 \): \[ K_p = K_c (RT)^{-1} = \frac{K_c}{RT} \] 4. **Analyze the Relationship**: Since \( R \) (the gas constant) and \( T \) (temperature) are both positive values, \( RT \) is greater than 1. Therefore: \[ K_p = \frac{K_c}{RT} \implies K_p < K_c \] This confirms that \( K_p \) is indeed less than \( K_c \). 5. **Conclusion**: - The assertion states that \( K_p \) is less than \( K_c \), which is true. - The reason provided explains the relationship correctly, stating that \( K_p \) is related to \( K_c \) as \( K_p = K_c (RT)^{\Delta n_g} \). Thus, both the assertion and the reason are correct, and the reason correctly explains the assertion. ### Final Answer: - **Assertion**: True - **Reason**: True - **Explanation**: The reason correctly explains the assertion.
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