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The molar solubility ( in mol L^(-1)) of...

The molar solubility ( in mol `L^(-1))` of a sparingly soluble salt `MX_(4)` is `'s'`. The corresponding solubility product `K_(sp), 's'` is given in terms of `K_(sp)` by the relation

A

`s=(256 K_(sp))^(1//5)`

B

`s=(128 K_(sp))^(1//4)`

C

`s=(K_(sp)//128)^(1//4)`

D

`s=(K_(sp)//256)^(1//5)`

Text Solution

Verified by Experts

The correct Answer is:
D

`MX_4 hArr M^(+)+4X^(-)`
If solubility is s, then
`[M^+]=s [X^-]=4s`
`K_(sp)=[M^+][X^-]^4`
`=(s)xx(4s)^4`
`=256s^5`
`therefore s=(K_(sp)//256)^(1//5)`
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