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CH3CH2CH=CH2 overset(B2H6)underset(H2O,H...

`CH_3CH_2CH=CH_2 overset(B_2H_6)underset(H_2O_,H_2O_2,OH^-)rarr Z`
What is Z?

A

`CH_3CH_2CH_2CH_2OH`

B

`CH_3CH_2CH(OH)CH_3`

C

`CH_3CH_2CH_2CHO`

D

`CH_3CH_2CH_2CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given problem, we will go through the hydroboration-oxidation reaction step by step. ### Step 1: Identify the Reactants The reactant provided is 1-butene, which is represented as CH₃CH₂CH=CH₂. The reagents used are B₂H₆ (diborane), followed by H₂O₂ (hydrogen peroxide) and OH⁻ (hydroxide ion). ### Step 2: Hydroboration In the hydroboration step, diborane (B₂H₆) reacts with the double bond in 1-butene. The boron atom from B₂H₆ acts as an electrophile and attaches to the less substituted carbon of the double bond (following Markovnikov's rule). - The double bond (C=C) in 1-butene attacks the boron atom, leading to the formation of a trialkylborane intermediate. In this case, the boron will attach to the terminal carbon (the less substituted carbon), and a carbocation will form on the more substituted carbon. ### Step 3: Formation of the Trialkylborane The structure after hydroboration can be represented as: - CH₃-CH₂-CH(BH₂)-CH₃ Here, the boron atom is attached to the terminal carbon, and a positive charge is on the more substituted carbon. ### Step 4: Oxidation In the oxidation step, we use H₂O₂ and OH⁻. The hydroxide ion (OH⁻) will attack the boron atom, leading to the replacement of the boron with a hydroxyl group (OH). - The reaction proceeds with the formation of an alkyl alcohol. The boron atom is replaced by a hydroxyl group, and we will have the final product as an alcohol. ### Step 5: Final Product After the oxidation step, the final product Z will be: - CH₃-CH₂-CH(OH)-CH₃, which is 2-butanol. ### Conclusion Thus, the final product Z is **2-butanol**. ---
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