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A constant volume thermometer using the ...

A constant volume thermometer using the gas reads a pressure of `1.75xx 10^(4)` Pa at normal freezing of water and reads` 2.39 xx 10^(4)` pa at normal boiling point of water. Obtained from the observation the temperature of absolute zero on celcius scale.

Text Solution

Verified by Experts

Let temperature on kelvin scale of freezing point of water =`=T_(1) K=2.93xx10^(4) Pa`
Let temperature on kelvin scale of boiling point of water `=T_(2)=K=1.75xx10^(4) Pa`
As volume is constant so by universal gas law
`PV=nRT`= as volume and mass of gas in thermometer constant, so
`P prop T or (P)/(T)`= constant
`(P_(1))/(T_(1))=(P_(2))/(T_(2))= or (T_(2))/(T_(1))=(P_(2))/(T_(1))=(2.39xx10^(4))/(1.75xx10^(4))=(239)/(175)`
s `T=t_(c)+ tT_(0) " "...(i)`
`T_(1)=0 +T_(0) " T_(2)= 100+T_(0)`
`:. (100+T_(0))/(T_(0))=(239)/(175)`
`(100)/(T_(0))+(T_(0))/(T_(0))=(239)/(175)`
`(100)/(T_(0))=(239-175)/(175)`
`:.(100)/(T)=(64)/(175)`
`64T_(0)=100xx175`
`T_(0)=(100xx175)/(64)=273`
From (1)
`t_(c)=T-T_(0)=0-273=-273K`
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