Home
Class 11
CHEMISTRY
Calculate the entropy change of n-hexane...

Calculate the entropy change of n-hexane when 1 mole of it evaporates at 341.7 K`(Delta_(vap) H = 29.0 kJ "mol"^(-1))`.

Text Solution

AI Generated Solution

The correct Answer is:
To calculate the entropy change (ΔS) of n-hexane when 1 mole of it evaporates at 341.7 K, we can use the formula: \[ \Delta S = \frac{\Delta H_{vap}}{T} \] where: - ΔS is the change in entropy, - ΔH_{vap} is the heat of vaporization, - T is the temperature in Kelvin. ### Step-by-Step Solution: 1. **Identify the values**: - ΔH_{vap} = 29.0 kJ/mol - T = 341.7 K 2. **Convert ΔH_{vap} from kJ to J**: \[ \Delta H_{vap} = 29.0 \, \text{kJ/mol} \times 1000 \, \text{J/kJ} = 29000 \, \text{J/mol} \] 3. **Substitute the values into the entropy change formula**: \[ \Delta S = \frac{29000 \, \text{J/mol}}{341.7 \, \text{K}} \] 4. **Calculate ΔS**: \[ \Delta S = \frac{29000}{341.7} \approx 84.87 \, \text{J/K/mol} \] 5. **Final Result**: The entropy change (ΔS) when 1 mole of n-hexane evaporates at 341.7 K is approximately: \[ \Delta S \approx 84.87 \, \text{J/K/mol} \]

To calculate the entropy change (ΔS) of n-hexane when 1 mole of it evaporates at 341.7 K, we can use the formula: \[ \Delta S = \frac{\Delta H_{vap}}{T} \] where: - ΔS is the change in entropy, ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    MODERN PUBLICATION|Exercise Advanced Level Problems|15 Videos
  • THERMODYNAMICS

    MODERN PUBLICATION|Exercise Conceptual Questions -1|19 Videos
  • THERMODYNAMICS

    MODERN PUBLICATION|Exercise Unit Practice Test|12 Videos
  • STRUCTURE OF ATOM

    MODERN PUBLICATION|Exercise Unit Practice Test|13 Videos

Similar Questions

Explore conceptually related problems

Calculate the entropy change of n -hexae when 1mol of it evaporates at 341.7K (Delta_(vap)H^(Theta) = 290.0 kJ mol^(-1))

Calculate the entropy change for vaporization of 1mol of liquid water to stem at 100^(@)C , if Delta_(V)H = 40.8 kJ mol^(-1) .

The entropy change when 36g of water evaporates at 373 K is :- (DeltaH=40.63(KJ)/(mol))

A swimmer coming out from a pool is covered with a film of water weighing about 18g. How much heat must be supplied to evaporate this water at 298 K ? Calculate the internal energy of vaporisation at 298K. Delta_("vap")H^(Ө) for water at 298K =44.01 kJ "mol"^(-1)

What is the enthalpy change when 1.0 g of water is frozen at 0^(@)C ? Delta_(fus) = H = 6.02 kJ "mol"^(-1) .

Calculate entropy changes of fusion and vaporisation for chlorine from the following data : Delta_(fus) H = 6.40 kJ "mol"^(-1) m.p = -102^(@)C Delta_(vap) H = 20.4 kJ mol^(-1) b.p = - 34^(@)C

MODERN PUBLICATION-THERMODYNAMICS-Practice Problems
  1. The enthalpy of vaporisation of benzene (C(6)H(6)) is 30.8 kJ mol^(-1)...

    Text Solution

    |

  2. Delta(vap)H^(@) for water is 40.73 kJ mol^(-1) and Delta(vap)S^(@) is ...

    Text Solution

    |

  3. Calculate the entropy change of n-hexane when 1 mole of it evaporates ...

    Text Solution

    |

  4. Calculate the Gibbs energy change on dissolving one mole of sodium chl...

    Text Solution

    |

  5. The value of DeltaH and DeltaS for two reactions are given below : R...

    Text Solution

    |

  6. At what temperature does the reduction of lead oxide to lead by carbon...

    Text Solution

    |

  7. For the reaction at 298 K 2A + B to C DeltaH = 40 kJ "mol"^(-1) a...

    Text Solution

    |

  8. Consider the reaction: 2NO(g)+O(2)(g) rarr 2NO(2)(g) Calculated th...

    Text Solution

    |

  9. Calculate the Delta(r)G^(@) for the reaction: C(6)H(12)O(6)(s) + 6O(...

    Text Solution

    |

  10. Calculate DeltaG^(@) for the reaction NO(g) iff 1/2 N(2)(g) + 1/2 O(...

    Text Solution

    |

  11. The equilibrium constant for the reaction CO(2)(g) +H(2)(g) hArr CO(...

    Text Solution

    |

  12. Calculated the equilibrium constant for the following reaction at 298K...

    Text Solution

    |

  13. The equilibrium constant for the reaction: CH(3)COOH(l) + C(2)H(5)OH...

    Text Solution

    |

  14. Calculate the entropy change for a reaction: XrarrY Given that Del...

    Text Solution

    |

  15. Calculate the equilibrium constant for the following reaction at 298K ...

    Text Solution

    |

  16. For the equilibrium reaction : 2H(2)(g) + O(2)(g) iff 2H(2)O(l) at 298...

    Text Solution

    |

  17. Calculate the equilibrium constant for the reaction : NO(g) + 1/2 O(2)...

    Text Solution

    |

  18. DeltaH^(Theta) and DeltaS^(Theta) for the reaction: Br(2)(l) +CI(2)(...

    Text Solution

    |

  19. Calculate the standard free energy change for the reaction : H(2)(g)...

    Text Solution

    |

  20. Calculate Delta(r)G^(@) for the reaction : CO(g) + 1/2O(2)(g) to CO(2)...

    Text Solution

    |