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In the reaction : Cl2+2OH^(-) rarr OCl^(...

In the reaction : `Cl_2+2OH^(-) rarr OCl^(-) +Cl^(-) +H_2O`

A

`OH^(-)` is oxidising and `Cl^(-)` is reducing agent

B

`Cl_2` is oxidising and `OH^(-)` is reducing agent

C

`OH^(-)` is both oxidising and reducing agent .

D

`Cl_2` is both oxidising and reducing agent

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The correct Answer is:
To determine the oxidizing and reducing agents in the reaction \( \text{Cl}_2 + 2\text{OH}^- \rightarrow \text{OCl}^- + \text{Cl}^- + \text{H}_2\text{O} \), we will follow these steps: ### Step 1: Assign Oxidation States We need to assign oxidation states to all the elements in the reaction. 1. **For \( \text{Cl}_2 \)**: Chlorine in its elemental form has an oxidation state of 0. 2. **For \( \text{OH}^- \)**: - Oxygen (O) has an oxidation state of -2. - Hydrogen (H) has an oxidation state of +1. 3. **For \( \text{OCl}^- \)**: - Let the oxidation state of Cl be \( x \). - The overall charge is -1, so we have: \[ x + (-2) = -1 \implies x = +1 \] - Therefore, the oxidation state of Cl in \( \text{OCl}^- \) is +1. 4. **For \( \text{Cl}^- \)**: Chlorine has an oxidation state of -1. 5. **For \( \text{H}_2\text{O} \)**: - Oxygen has an oxidation state of -2. - Each Hydrogen has an oxidation state of +1. ### Step 2: Identify Changes in Oxidation States Now we will summarize the oxidation states: - In \( \text{Cl}_2 \): Cl = 0 - In \( \text{OCl}^- \): Cl = +1 - In \( \text{Cl}^- \): Cl = -1 Now let's analyze the changes: - The chlorine in \( \text{Cl}_2 \) (0) is oxidized to \( \text{OCl}^- \) (+1). - The chlorine in \( \text{Cl}_2 \) (0) is reduced to \( \text{Cl}^- \) (-1). ### Step 3: Determine the Oxidizing and Reducing Agents - **Oxidizing Agent**: The species that gets reduced (gains electrons) is the oxidizing agent. Here, \( \text{Cl} \) in \( \text{OCl}^- \) is the oxidizing agent since it goes from 0 to +1. - **Reducing Agent**: The species that gets oxidized (loses electrons) is the reducing agent. Here, \( \text{Cl} \) in \( \text{Cl}^- \) is the reducing agent since it goes from 0 to -1. ### Conclusion In this reaction: - \( \text{Cl}_2 \) acts as both an oxidizing agent (for the formation of \( \text{OCl}^- \)) and a reducing agent (for the formation of \( \text{Cl}^- \)). ### Final Answer Thus, \( \text{Cl}_2 \) is both the oxidizing agent and the reducing agent in this reaction. ---
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MODERN PUBLICATION-REDOX REACTIONS -COMPETITION FILE (Objective Questions) (A. MULTIPLE CHOICE QUESTIONS)
  1. Oxidation state of sulphur in Caro's acid is

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  2. What is the oxidation state of sodium in sodium amalgam (Na//Hg)?

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  3. In the reaction : Cl2+2OH^(-) rarr OCl^(-) +Cl^(-) +H2O

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  4. The oxidation states of S in S2O8^(2-) is

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  5. In which of the following compounds , the oxidation number of carbon i...

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  6. The oxidation states of V and Br in V (BrO2)2 are respectively

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  7. The oxidation state of N in HN3 is

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  8. In which of the following S has highest oxidation state ?

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  9. Which of the following rules for oxidation number is not correct?

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  10. In the reaction : 3CuO+2NH3 rarr N2+3H2O+3Cu the change of NH3 to ...

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  11. Which of the following statement is not correct ?

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  12. When phosphorus reacts with caustic soda, the products are PH(3) and N...

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  13. Which of the following is not an example of redox reaction ?

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  14. The oxidation state of Cr in Cr(CO)6 is

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  15. Oxidation state of oxygen in H(2)O(2) is

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  16. The oxidation state of phosphorus in Ba(H2PO2)2 is

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  17. The oxidation number of S in S8, S2F2 and H2S respectively are :

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  18. In the reaction : 3Br2+6CO3^(2-)+3H2O rarr 5Br^(-) +BrO3^(-) +6HCO3...

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  19. Oxidation state of Fe in Fe(3)O4 is

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  20. In Br(3)O8 compound , oxidation number of bromine is

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