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How would you carry out the following co...

How would you carry out the following conversions ?
(a) `H_(3)C CH_(2)=CH_(2) to H_(3)C- CH_(2)CH_(2)CH_(2)OH`
(b) `H_(3)C CH_(2)-CH =CH_(2) to H_(3)C-CH_(2)-CH(OH)CH_(2)OH`
(c) `H_(3)C C-= CH to H_(3)C COCH_(3)`
(d) `Br_(2)CH CHBr_(2) to HC -=CH`

Text Solution

Verified by Experts

(a) `H_(3)C CH_(2)=CH_(2) overset("B_(2)H_(6), H_(2)O_(2), OH^(-))to H_(3)C- CH_(2)CH_(2)CH_(2)OH`
(b) `H_(3)CCH_(2)-CH =CH_(2) overset("Alk. KMnO_(4))to H_(3)C-CH_(2)-CH(OH)CH_(2)OH`
(c) `H_(3)C C-= CH underset(Hg^(2+))overset(H_(2)SO_(4))to CH_(3)underset(OH)underset(|)CH=CH_(2) overset("Rearrangement")to CH_(3)underset(O)underset(||)C CH_(3)`
(d) `Br_(2)CH CHBr_(2) overset(Zn)to HC -=CH`
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