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In the reaction : HC -= CH overset(NaN...

In the reaction :
`HC -= CH overset(NaNH_(2)) to overset(CH_(3)I)to Y underset(H^(+))overset(H_(2)O, Hg^(2+))to Z`,

A

`CH_(3)CHO`

B

`CH_(3)CH_(2)CH=CH_(2)`

C

`CH_(3)COCH_(3)`

D

`CH_(3)CH_(2)CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the reaction step by step, let's break down the transformations occurring in the reaction. ### Step 1: Identify the starting material The starting material is **ethyne (HC≡CH)**. ### Step 2: Reaction with sodium amide (NaNH₂) When ethyne reacts with sodium amide (NaNH₂), it undergoes deprotonation. The hydrogen atom attached to the carbon atom is replaced by a sodium ion (Na⁺), resulting in the formation of a **sodium acetylide**. **Reaction:** \[ HC≡CH + NaNH₂ \rightarrow HC≡C^{-}Na^{+} \] **Product X:** Sodium acetylide (HC≡C⁻Na⁺) ### Step 3: Reaction with methyl iodide (CH₃I) Next, sodium acetylide reacts with methyl iodide (CH₃I). In this step, the acetylide ion (HC≡C⁻) acts as a nucleophile and attacks the electrophilic carbon in methyl iodide, leading to the formation of a new carbon-carbon bond. **Reaction:** \[ HC≡C^{-}Na^{+} + CH₃I \rightarrow HC≡C-CH₃ + NaI \] **Product Y:** Propyne (HC≡C-CH₃) ### Step 4: Reaction with water (H₂O) and mercuric ion (Hg²⁺) The propyne (Y) then undergoes hydration in the presence of water and mercuric ion (Hg²⁺) in an acid-catalyzed reaction. This step converts the alkyne into an alcohol through the Markovnikov addition of water. **Reaction:** \[ HC≡C-CH₃ + H₂O \overset{Hg^{2+}}{\rightarrow} CH₃-CHOH-CH₃ \] **Product Z:** 2-Propanol (CH₃-CHOH-CH₃) ### Summary of Products: - **X:** Sodium acetylide (HC≡C⁻Na⁺) - **Y:** Propyne (HC≡C-CH₃) - **Z:** 2-Propanol (CH₃-CHOH-CH₃)

To solve the reaction step by step, let's break down the transformations occurring in the reaction. ### Step 1: Identify the starting material The starting material is **ethyne (HC≡CH)**. ### Step 2: Reaction with sodium amide (NaNH₂) When ethyne reacts with sodium amide (NaNH₂), it undergoes deprotonation. The hydrogen atom attached to the carbon atom is replaced by a sodium ion (Na⁺), resulting in the formation of a **sodium acetylide**. ...
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MODERN PUBLICATION-HYDROCARBONS-COMPETITION FILE (OBJECTIVE TYPE QUESTIONS) (MULTIPLE CHOICE QUESTIONS WITH ONLY ONE CORRECT ANSWER)
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  4. Number of acidic hydrogen atoms in but-1-yne is

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  5. The alkene which will react with KMnO(4) to give pyruvic acid is

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  6. Ethyne adds a molecule of methyl alcohol in the presence of alkali to ...

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  8. C(2)H(2) underset( H(2)SO(4))overset( Hg(OH)(2) 1%) (rarr) A overset( ...

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  9. Products of the following reaction are CH(3)-underset(CH(3))underset...

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  12. An aromatic compound C(7)H(7)Cl on oxidation gives another aromatic co...

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  13. Which of the following species is less reactive than benzene towards r...

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  14. In benzene, each carbon atom undergoes

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  15. Number of pi-bonds in naphthalene is

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  16. In the reaction, C(6)H(6)+ RCOCl overset(AlCl(3))to C(6)H(5)COR+ HCl...

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  17. Benzene reacts with CH(3)Cl in the presence of anyhydrous AlCl(3) to f...

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  18. Benzene reacts with CH(3)COCl in the presence of anhydrous AlCl(3) to ...

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  19. The attacking reagent in electrophilic sulphonation of benzene is

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  20. In Friedel Craft Reaction, anhydrous AlCl(3) is used. Its function is ...

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