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Which of the folllowing on treatment wit...

Which of the folllowing on treatment with warm dil. `H_(2)SO_(4)` in the presence of `HgSO_(4)` will give butan-2-one?

A

But-1-yne

B

But-1-ene

C

But-2-yne

D

Pent-1-yne

Text Solution

Verified by Experts

The correct Answer is:
A, C

`underset("But-1-yne")(HC -= C- CH_(2)- CH_(3)+ H_(2)O) overset(Hg^(2+),H^(+))to CH_(2)= underset(OH)underset(|)C- CH_(2)CH_(3) to CH_(3)- underset(O)underset(||)C- CH_(2)CH_(3)`
`underset("But-2-yne")(CH_(3)- C -= C- CH_(3)+ H_(2)O) overset(Hg^(2+),H^(+))to CH_(3)-CH= underset(O)underset(||)C-CH_(3) to CH_(3)CH_(2)- underset(O)underset(||)C- CH_(3)`
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