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Arrange the folliwing compounds in incre...

Arrange the folliwing compounds in increasing order of `SN^(-2)` reactivity.
a. I.m `ClCH_(2)CH = CHCH_(2)CH_(3)`
II. `CH_(3)C(Cl) = CHCH_(2) CH_(3)`
III. `CH_(3)CH = CHCH_(2)CH_(2)Cl`
IV. `CH_(3)CH = CHCH_(2)(Cl) CH_(3)`
b. I. `CH_(3)CH_(2)Br`
II. `CH_(2) = CHCH(Br) CH_(3)`
III. `CH_(2) = CHBr`
IV. `CH_(3)CH (Br) CH_(3)`
C. I. `(CH_(3))_(3)CCl`, II. `C_(6)H_(5)C(CH_(3))_(2)Cl`
III. `(CH_(3))_(2)CHCl`, IV. `CH_(3)CH_(2)CH_(2)Cl`

Text Solution

Verified by Experts

(i) `CH_(2)=CHBr lt CH_(3)CH_(2)Br lt CH_(3)CH(Br)CH_(3) lt CH_(2)=CHCH(Br)CH_(3)`
(ii) `CH_(3)C(Cl)=CHCH_(2)CH_(3) lt CH_(3)CH=CHCH_(2)CH_(2)Cl lt ClCH_(2)CH=CHCH_(2)CH_(3) lt CH_(3)CH=CHCH(Cl)CH_(3)`
(iii) `CH_(3)CH_(2)CH_(2)Cl lt (CH_(3))_(2)CHCl lt (CH_(3))_(3)C Cl lt C_(6)H_(5)C(CH_(3))_(2)Cl`
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