Boiling point of tert-butyl bromide is `"less" // "more"` than that of n-butylbromide.

Explanation

To determine whether the boiling point of tert-butyl bromide is less or more than that of n-butyl bromide, we need to analyze the factors that influence boiling points, particularly focusing on the intermolecular forces present in each compound.

### Step-by-Step Solution:

1. **Understanding Boiling Point**: The boiling point of a substance is influenced by the strength of intermolecular forces. The stronger the intermolecular forces, the higher the boiling point.

2. **Identifying the Compounds**:
- Tert-butyl bromide (tert-C4H9Br) has the structure:
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