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The reaction : RX + 2Na + RX overset("...

The reaction :
`RX + 2Na + RX overset("Dry ether")to R-R + 2NaX` is called :

A

Sandmeyer's reaction

B

Fittig reaction

C

Wurtz reaction

D

Williamson's synthesis.

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The correct Answer is:
To solve the question regarding the reaction \( RX + 2Na \overset{\text{Dry ether}}{\rightarrow} R-R + 2NaX \), we need to identify the name of this reaction. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in the given reaction are \( RX \) (an alkyl halide) and \( Na \) (sodium metal). 2. **Understand the Reaction Conditions**: - The reaction takes place in the presence of dry ether, which is a common solvent used in organic reactions. 3. **Analyze the Products**: - The products of the reaction are \( R-R \) (a new carbon-carbon bond formed between two alkyl groups) and \( 2NaX \) (where \( X \) is a halogen). 4. **Recognize the Type of Reaction**: - This reaction is a coupling reaction where two alkyl halides are coupled to form a new alkane. It is specifically a reaction that involves the formation of a new carbon-carbon bond. 5. **Name the Reaction**: - The reaction described is known as the **Wurtz Reaction**. It is characterized by the coupling of alkyl halides using sodium in dry ether. 6. **Choose the Correct Option**: - Based on the analysis, the correct answer to the question is that this reaction is called the **Wurtz Reaction**. ### Final Answer: The reaction \( RX + 2Na \overset{\text{Dry ether}}{\rightarrow} R-R + 2NaX \) is called the **Wurtz Reaction**. ---
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Wurtz reaction involves the comdensation of two molecules of alkyl halides in the presence of sodium and dry ether R-X+2Na+R-Xoverset("dry ether")toR-R+2NaX In this reaction small amount of alkene is also formed as by product. CH_(3)CH_(2)Br+CH_(3)CH_(2)Broverset("Na/dry ether")toCH_(3)-CH_(2)-CH_(2)-CH_(3)+underset("By-product")ubrace(CH_(2)=CH_(2)+CH_(3)-CH_(3)) Tertiary alkyl halides do not give wurtz reaction. Frankland reaction is similar but has certain advantages over wurtz reaction. it is useful in the synthesis of symmetrical alkanes. frankland reaction is shown by primary, Secondary as well as tertiary alkyl halide. Q. Which among the followng compound will give wurtz reaction with good yield ?

Wurtz reaction involves the comdensation of two molecules of alkyl halides in the presence of sodium and dry ether R-X+2Na+R-Xoverset("dry ether")toR-R+2NaX In this reaction small amount of alkene is also formed as by product. CH_(3)CH_(2)Br+CH_(3)CH_(2)Broverset("Na/dry ether")toCH_(3)-CH_(2)-CH_(2)-CH_(3)+underset("By-product")ubrace(CH_(2)=CH_(2)+CH_(3)-CH_(3)) Tertiary alkyl halides do not give wurtz reaction. Frankland reaction is similar but has certain advantages over wurtz reaction. it is useful in the synthesis of symmetrical alkanes. frankland reaction is shown by primary, Secondary as well as tertiary alkyl halide. Q. A mixture of ethyl iodide and methyl iodide is subjected to wurtz reaction. the product that will not formed is

MODERN PUBLICATION-HALOALKANES AND HALOARENES-REVISION EXERCISE (Objective Questions) (Multiple choice questions)
  1. The IUPAC name of (CH(3))(3)C Cl is

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  2. Which of the following is not a chiral ?

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  3. The reaction : RX + 2Na + RX overset("Dry ether")to R-R + 2NaX is ca...

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  4. In S(N)1 reaction, the order of reactivity of halides is

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  5. C-X bond is strongest in :

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  6. Reactivity order of halides of dehydrohalogenation is

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  7. Which one of the following gives only one monochloro derivative?

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  8. D.D.T. is prepared by heating chlorobenzene with:

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  9. C(2)H(5)Cl on heating with alcoholic KOH will produce

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  10. Alkyl halides are less soluble in water because

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  11. Among the following, which one is chlorine containing insecticide?

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  12. The boiling points of haloalkanes follow the order:

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  13. Which of the following has highest dipole moment in the following ?

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  14. Which of the following is not a polyhalogen compound?

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  15. The ease of dehydrohalogenation of alkyl halide with alcoholic KOH is-

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  16. Alkyl halides are prepared from alcohol by treating with:

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  17. Organic compound which shows complete stereochemical inversion during ...

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  18. Which of the following reaction is most suitable for the preparation o...

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  19. The reaction is:

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  20. In the given alkyl halides which one has minimum boiling point?

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