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In the reaction : CH(3)CHCl(2) overset...

In the reaction :
`CH_(3)CHCl_(2) overset("aq. KOH")to "Intermediate" to X`, X is :

A

`CH_(3)CHO`

B

`(CH_(3))_(2)CO`

C

`CH_(3)CH_(2)OH`

D

`underset(OH)underset(|)CH_(2)-underset(OH)underset(|)CH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction step by step: ### Step 1: Identify the Reactant The reactant given is CH₃CHCl₂, which is 1,1-dichloroethane. ### Step 2: Understand the Role of Aqueous KOH Aqueous KOH acts as a nucleophile in this reaction. In this context, it will facilitate a nucleophilic substitution reaction where the chlorine atoms (Cl) will be replaced by hydroxyl groups (OH). ### Step 3: Nucleophilic Substitution Reaction In the presence of aqueous KOH, the two chlorine atoms in CH₃CHCl₂ will be substituted by hydroxyl groups. This means that the reaction will proceed as follows: - The first chlorine atom (Cl) is replaced by OH, resulting in CH₃CH(OH)Cl. - The second chlorine atom (Cl) is then replaced by another OH, leading to CH₃C(OH)(OH). ### Step 4: Formation of the Intermediate The intermediate formed after both substitutions is CH₃C(OH)₂. This compound has two hydroxyl groups on the same carbon, which is not stable. ### Step 5: Elimination of Water To stabilize the intermediate, a water molecule is eliminated. This can occur by taking one hydroxyl group (OH) and one hydrogen atom (H) from the adjacent carbon, resulting in the formation of a double bond. ### Step 6: Final Product (X) After the elimination of water, the final product (X) is formed, which is CH₃CH=O. This compound is an aldehyde known as acetaldehyde. ### Conclusion Thus, the product X formed from the reaction of CH₃CHCl₂ with aqueous KOH is acetaldehyde (CH₃CHO). ### Answer X is CH₃CHO (acetaldehyde). ---

To solve the problem, we need to analyze the reaction step by step: ### Step 1: Identify the Reactant The reactant given is CH₃CHCl₂, which is 1,1-dichloroethane. ### Step 2: Understand the Role of Aqueous KOH Aqueous KOH acts as a nucleophile in this reaction. In this context, it will facilitate a nucleophilic substitution reaction where the chlorine atoms (Cl) will be replaced by hydroxyl groups (OH). ...
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MODERN PUBLICATION-HALOALKANES AND HALOARENES-A. MULTIPLE CHOICE QUESTIONS (with only one correct answer)
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