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The major product in the reaction is C...

The major product in the reaction is
`CH_(3)-underset(CH_(3))underset(|)CH-CH_(2)Br underset(CH_(3)OH)overset(CH_(3)O^(-))to`

A

`CH_(3)-underset(OCH_(3))underset(|)CH-CH_(2)CH_(3)`

B

`CH_(3)-underset(CH_(3))underset(|)C=CH_(2)`

C

`CH_(3)-underset(CH_(3))underset(|)CHCH_(2)OCH_(3)`

D

`CH_(3)-underset(OCH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the major product of the reaction between the given alkyl halide and methoxide ion in methanol, we can follow these steps: ### Step 1: Identify the Reactants The reactants are: - An alkyl halide: `CH3-CH(CH3)-CH2Br` - A nucleophile/base: Methoxide ion (`CH3O^(-)`) - A solvent: Methanol (`CH3OH`) ### Step 2: Analyze the Reaction Conditions The methoxide ion is a strong nucleophile and a strong base. In the presence of a bulky alkyl halide, we need to consider whether a substitution (SN2) or elimination (E2) reaction will occur. ### Step 3: Consider Steric Hindrance The alkyl halide has two methyl groups adjacent to the carbon that is bonded to the bromine atom. This creates significant steric hindrance, making it difficult for the methoxide ion to perform a backside attack necessary for an SN2 reaction. ### Step 4: Determine the Reaction Type Due to the steric hindrance from the two adjacent methyl groups, the SN2 pathway is not favored. Instead, the methoxide ion will act as a base and abstract a proton from the β-carbon (the carbon adjacent to the one bonded to Br). This leads to an elimination reaction (E2). ### Step 5: Perform the Elimination Reaction 1. The methoxide ion abstracts a proton from the β-carbon. 2. The bromine atom (leaving group) departs, resulting in the formation of a double bond between the α and β carbons. ### Step 6: Write the Major Product The major product of the elimination reaction is: - An alkene: `CH3-CH=CH-CH3` (butene) ### Final Product The major product of the reaction is **butene**. ---

To determine the major product of the reaction between the given alkyl halide and methoxide ion in methanol, we can follow these steps: ### Step 1: Identify the Reactants The reactants are: - An alkyl halide: `CH3-CH(CH3)-CH2Br` - A nucleophile/base: Methoxide ion (`CH3O^(-)`) - A solvent: Methanol (`CH3OH`) ...
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MODERN PUBLICATION-HALOALKANES AND HALOARENES-A. MULTIPLE CHOICE QUESTIONS (with only one correct answer)
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  7. 1,3-Dibromopropane reacts with metallic zinc to form

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  8. Identify the set of "reagents" // "reaction" conditions 'X' and 'Y' in...

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  9. Butane nitrile may be prepared by heating

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  10. Which of the following will be least reactive in nucleophilic substitu...

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  11. The most reactive nucleophile among the following is

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  12. In the reaction, the major product 'X' is

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  13. Chlorobenzene can be obtained from benzene diazonium chloride by

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  14. Which of the following is most reactive toward nucleophilic substituti...

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  15. The reaction fo toluenec with Cl(2) in presence of FeCl(3) gives predi...

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  16. During the conversion : C(6)H(5)CH(2)CH(3) overset((a))to X overset(...

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  17. The increasing order of hydrolysis of the following compounds is

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  18. Arrange the following compounds in order of increasing dipole moment, ...

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  19. In the following sequence of reactions, B is C(6)H(6) underset(FeCl(...

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  20. 2-Phenyl-2-chloropropane on treatment with alc. KOH gives mainly

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