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2-Phenyl-2-chloropropane on treatment wi...

2-Phenyl-2-chloropropane on treatment with alc. KOH gives mainly

A

2-Phenylpropene

B

3-Phenylpropene

C

1-Phenylpropan-2-ol

D

1-Phenylpropan-3-ol

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The correct Answer is:
To solve the question regarding the reaction of 2-Phenyl-2-chloropropane with alcoholic KOH, we can follow these steps: ### Step 1: Understand the Reactants 2-Phenyl-2-chloropropane has the following structure: - It consists of a propane chain (3 carbon atoms) with a phenyl group (C6H5) attached to the second carbon and a chlorine (Cl) atom also attached to the second carbon. - The structure can be represented as: ``` Cl | C6H5-C-CH3 | CH2 ``` ### Step 2: Identify the Role of Alcoholic KOH Alcoholic KOH serves as a strong base. In this reaction: - The hydroxide ion (OH-) can act as a base and will abstract a proton (H+) from a β-hydrogen (hydrogen atom on the carbon adjacent to the carbon bearing the leaving group, Cl). - The reaction will lead to the elimination of HCl. ### Step 3: Determine the β-Hydrogens In 2-Phenyl-2-chloropropane, the β-hydrogens are on the carbon atoms adjacent to the carbon with the Cl group. Here, both β-hydrogens are equivalent due to the symmetrical nature of the molecule. ### Step 4: Elimination Reaction When alcoholic KOH abstracts a β-hydrogen, HCl is eliminated: - The elimination of HCl leads to the formation of a double bond between the two adjacent carbon atoms. - The reaction can be represented as follows: ``` Cl H | | C6H5-C-CH3 + KOH → C6H5-C=CH2 + HCl + KCl + H2O | CH2 ``` ### Step 5: Final Product The major product of this elimination reaction is: - **1-Phenylpropene**, which has the structure: ``` C6H5 | CH=CH-CH3 ``` ### Conclusion Thus, the main product formed when 2-Phenyl-2-chloropropane is treated with alcoholic KOH is **1-Phenylpropene**. ---

To solve the question regarding the reaction of 2-Phenyl-2-chloropropane with alcoholic KOH, we can follow these steps: ### Step 1: Understand the Reactants 2-Phenyl-2-chloropropane has the following structure: - It consists of a propane chain (3 carbon atoms) with a phenyl group (C6H5) attached to the second carbon and a chlorine (Cl) atom also attached to the second carbon. - The structure can be represented as: ``` ...
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