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Which of the following statements are co...

Which of the following statements are correct ?

A

Benzyl halides are more reactive than vinyl and aryl halides

B

Vinyl halides are more reactive than alkyl halides

C

Aryl halides are less reactive than alkyl halides

D

Aryl halides are more reactive than benzyl halides

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statements about halides are correct, we will analyze each option provided in the question step by step. ### Step 1: Understand the Types of Halides 1. **Benzyl Halide**: Contains a benzene ring with a -CH2X group (where X is a halogen). 2. **Vinyl Halide**: Contains a double bond with the structure CH2=CHX. 3. **Alkyl Halide**: Contains a structure like R-X, where R is an alkyl group. 4. **Aryl Halide**: Contains a halogen directly attached to a benzene ring. ### Step 2: Analyze Each Option - **Option A**: "Benzyl Halides are more reactive than Vinyl and Aryl Halides." - **Analysis**: Benzyl halides have a single bond (C-X) which is more reactive than the partial double bond character found in vinyl and aryl halides. Therefore, this statement is **correct**. - **Option B**: "Vinyl Halides are more reactive than Alkyl Halides." - **Analysis**: Vinyl halides have a double bond character which makes them less reactive than alkyl halides that have a pure single bond. Thus, this statement is **incorrect**. - **Option C**: "Aryl Halides are less reactive than Alkyl Halides." - **Analysis**: Aryl halides have a partial double bond character due to resonance with the benzene ring, making them less reactive than alkyl halides which have a pure single bond. Therefore, this statement is **correct**. - **Option D**: "Aryl Halides are more reactive than Benzyl Halides." - **Analysis**: As established, benzyl halides are more reactive than aryl halides due to the absence of resonance stabilization in the C-X bond. Thus, this statement is **incorrect**. ### Conclusion The correct statements are: - **Option A**: Benzyl Halides are more reactive than Vinyl and Aryl Halides. - **Option C**: Aryl Halides are less reactive than Alkyl Halides. ### Final Answer The correct statements are **A and C**.
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