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The number of reactions proceeding throu...

The number of reactions proceeding through free radical mechanism are
(i) `C_(2)H_(5)Br+Na^(+)""^(-)OCH_(3)`
(ii) `C_(2)H_(5)Br+AgCN`
(iii) `C_(6)H_(5)CH_(3)+Cl_(2)(hv)`
(iv) `CH_(3)CH=CH_(2)+HBr` (peroxides)
(v) `C_(2)H_(5)Br+alc.KOH`
(vi) `CH_(3)CH=CH_(2)+HCl`(peroxide)
(vii) `C_(2)H_(5)Br+H_(2)(Ni "or" Pd)`
(viii) `C_(2)H_(6)+Cl_(2)(hv)`
(ix) `C_(2)H_(5)Br+NaSH`

Text Solution

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The correct Answer is:
To determine the number of reactions proceeding through a free radical mechanism from the given options, we will analyze each reaction step by step. ### Step-by-Step Solution: 1. **Reaction (i): `C2H5Br + Na+ OCH3-`** - This is a nucleophilic substitution reaction (SN2) where the methoxide ion (OCH3-) acts as a nucleophile. - **Mechanism:** Nucleophilic substitution (not free radical). - **Conclusion:** Not a free radical reaction. 2. **Reaction (ii): `C2H5Br + AgCN`** - This is also a nucleophilic substitution reaction where AgCN acts as a nucleophile. - **Mechanism:** Nucleophilic substitution (not free radical). - **Conclusion:** Not a free radical reaction. 3. **Reaction (iii): `C6H5CH3 + Cl2 (hv)`** - This reaction involves benzene (C6H5) and chlorine (Cl2) in the presence of light (hv), which promotes free radical formation. - **Mechanism:** Free radical halogenation. - **Conclusion:** This is a free radical reaction. 4. **Reaction (iv): `CH3CH=CH2 + HBr (peroxides)`** - The presence of peroxides leads to the peroxide effect, which results in a free radical mechanism for the addition of HBr to alkenes. - **Mechanism:** Free radical addition. - **Conclusion:** This is a free radical reaction. 5. **Reaction (v): `C2H5Br + alc. KOH`** - This is an elimination reaction (E2) where alcoholic KOH removes a hydrogen halide. - **Mechanism:** Elimination (not free radical). - **Conclusion:** Not a free radical reaction. 6. **Reaction (vi): `CH3CH=CH2 + HCl (peroxide)`** - The peroxide effect does not apply to HCl; hence, this reaction does not proceed via a free radical mechanism. - **Mechanism:** Not free radical. - **Conclusion:** Not a free radical reaction. 7. **Reaction (vii): `C2H5Br + H2 (Ni or Pd)`** - This is a reduction reaction where hydrogen is added to the alkyl bromide. - **Mechanism:** Reduction (not free radical). - **Conclusion:** Not a free radical reaction. 8. **Reaction (viii): `C2H6 + Cl2 (hv)`** - This reaction involves ethane and chlorine in the presence of light, leading to free radical formation and substitution. - **Mechanism:** Free radical halogenation. - **Conclusion:** This is a free radical reaction. 9. **Reaction (ix): `C2H5Br + NaSH`** - This is a nucleophilic substitution reaction where NaSH acts as a nucleophile. - **Mechanism:** Nucleophilic substitution (not free radical). - **Conclusion:** Not a free radical reaction. ### Summary of Free Radical Reactions: - The reactions that proceed through a free radical mechanism are: - (iii) `C6H5CH3 + Cl2 (hv)` - (iv) `CH3CH=CH2 + HBr (peroxides)` - (viii) `C2H6 + Cl2 (hv)` ### Total Count: - **Total Free Radical Reactions:** 3 ### Final Answer: The number of reactions proceeding through free radical mechanism is **3**.

To determine the number of reactions proceeding through a free radical mechanism from the given options, we will analyze each reaction step by step. ### Step-by-Step Solution: 1. **Reaction (i): `C2H5Br + Na+ OCH3-`** - This is a nucleophilic substitution reaction (SN2) where the methoxide ion (OCH3-) acts as a nucleophile. - **Mechanism:** Nucleophilic substitution (not free radical). - **Conclusion:** Not a free radical reaction. ...
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