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Write the structure of the major product...

Write the structure of the major product and IUPAC name in each of the following reactions :
(i) `CH_(3)CH_(2)CH_(2)Cl+NaI underset("Heat")overset("Acetone")to`
(ii) `CH_(3)CH_(2)Cl + SbF_(3) overset("Heat")rarr`
(iii) `CH_(3)CH_(2)CH_(2)OH +SOCl_(2) rarr`
(iv) `CH_(3)CH_(2)CH=CH_(2)+HBr overset("Peroxide")rarr`
(v) `CH_(3)CH_(2)underset(CH_(3))underset(|)C=CH_(2)+HBr overset("No Peroxide")rarr`
(vi) `CH_(3)CH_(2)CH_(2)Br+Hg_(2)F_(2) rarr`
(vii) `CH_(3)CH_(2)C-= CH+HCl ("1-equiv") rarr`
(viii) `CH_(3)CH=CH_(2)+Cl_(2)overset(773-873k)rarr`

Text Solution

Verified by Experts

(i) `CH_(3)CH_(2)CH_(2)Cl+NaI underset("Heat")overset("Acetone")to underset("Iodopropane")(CH_(3)CH_(2)CH_(2)I)+NaCl`
This reaction is called Finkelstein reaction.
(ii) `3CH_(3)CH_(2)Cl + 2SbF_(3) overset("Heat")rarr underset("Fluoroethane")(3CH_(3)CH_(2)F)+2SbCl_(3)`
(iii) `CH_(3)CH_(2)CH_(2)OH +SOCI_(2) rarr underset("1-Chloropropane")(CH_(3)CH_(2)CH_(2)Cl)+SO_(2)+HCl`
(iv) `CH_(3)CH_(2)CH=CH_(2)+HBr overset("Peroxide")rarr underset("1-Bromobutane")(CH_(3)CH_(2)CH_(2)-CH_(2)Br)`
(v) `CH_(3)CH_(2)underset(CH_(3))underset(|)C=CH_(2)+HBr overset("No Peroxide")rarr underset("2-Bromo-2methylbutane")(CH_(3)CH_(2)underset(Br)underset(|)overset(CH_(3))overset(|)C-CH_(3))`
(vi) `2CH_(3)CH_(2)CH_(2)Br+Hg_(2)F_(2) rarr underset("1-Fluoropropane")(2CH_(3)CH_(2)CH_(2)F)+Hg_(2)Br_(2)`
(vii) `CH_(3)CH_(2)C-= CH+HCl ("1-equiv") overset("No Peroxide")rarr underset("2-Chlorobut-1-ene")(CH_(3)CH_(2)underset(Cl)underset(|)C=CH_(2))`
(viii) `CH_(3)CH=CH_(2)+Cl_(2)overset(773-873k)underset("Vapour phase")rarr underset("3-Chloroprop-1-ene")(ClCH_(2)CH=CH_(2))+HCl`
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