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Arrange the following in increasing orde...

Arrange the following in increasing order of their expected `S_(N)1` reactivity :
(i) `CH_(3)CH(Br)CH_(3), CH_(3)CH_(2)Br, CH_(2)=CHBr, CH_(2)=CHCH(Br)CH_(3)`
(ii) `ClCH_(2)CH=CHCH_(2)CH_(3), CH_(3)C(Cl)=CHCH_(2)CH_(3), CH_(3)CH=CHCH_(2)CH_(2)Cl, CH_(3)CH=CHCH(Cl)CH_(3)`
(iii) `(CH_(3))_(3)C Cl, C_(6)H_(5)C(CH_(3))_(2)Cl,(CH_(3))_(2)CHCl, CH_(3)CH_(2)CH_(2)Cl`

Text Solution

Verified by Experts

(i) `CH_(2)=CHBr lt CH_(3)CH_(2)Br lt CH_(3)CH(Br)CH_(3) lt CH_(2)=CHCH(Br)CH_(3)`
(ii) `CH_(3)C(Cl)=CHCH_(2)CH_(3) lt CH_(3)CH=CHCH_(2)CH_(2)Cl lt ClCH_(2)CH=CHCH_(2)CH_(3) lt CH_(3)CH=CHCH(Cl)CH_(3)`
(iii) `CH_(3)CH_(2)CH_(2)Cl lt (CH_(3))_(2)CHCl lt (CH_(3))_(3)C Cl lt C_(6)H_(5)C(CH_(3))_(2)Cl`
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