From each of the following pairs, predict which compound will have higher boiling point:
(i) isopropyl bromide and n-propyl bromide (ii) bromoethane and iodoethane
(iii) tert-butyl chloride and tert-butyl iodide (iv) iso-propyl bromide and n-butyl bromide

Explanation

To predict which compound will have a higher boiling point from each of the given pairs, we need to consider two main factors: molecular weight and the surface area of the molecules, which affects the magnitude of Van der Waals forces. Let's analyze each pair step by step.

### Step-by-Step Solution:

**(i) Isopropyl bromide vs. n-propyl bromide**

1. **Molecular Structure**:
- Isopropyl bromide (C3H7Br) has a branched structure.
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