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Out of HCl (g) and SOCl(2) which is pref...

Out of HCl (g) and `SOCl_(2)` which is preferred for converting ethanol into chloroethane?

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To convert ethanol (CH3CH2OH) into chloroethane (CH3CH2Cl), we can use either HCl (g) or thionyl chloride (SOCl2). Let's analyze both methods step by step to determine which is preferred. ### Step 1: Reaction with HCl 1. **Starting Material**: Ethanol (CH3CH2OH). 2. **Protonation**: The hydroxyl group (-OH) of ethanol can be protonated by HCl, forming an oxonium ion (CH3CH2OH2+). 3. **Nucleophilic Attack**: The oxonium ion is a better leaving group. The water molecule (H2O) leaves, creating a carbocation (CH3CH2+). 4. **Chloride Ion Attack**: The chloride ion (Cl-) from HCl attacks the carbocation, resulting in the formation of chloroethane (CH3CH2Cl). 5. **Byproduct**: The reaction produces water as a byproduct. ...
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MODERN PUBLICATION-HALOALKANES AND HALOARENES-CONCEPTUAL QUESTIONS
  1. Which of the following two reactions is S(N)2 and why?

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  2. Chloroform contains chlorine but gives no reaction with AgNO(3) soluti...

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  3. Out of HCl (g) and SOCl(2) which is preferred for converting ethanol i...

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  4. Chloroform is stored in dark coloured bottles. Explain in not more t...

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  5. Haloarenes are insoluble in water but are soluble in benzene. Explain.

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  6. The p-isomer of dichlorobenzene has higher melting point than o-and m-...

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  7. Iodoform gives a precipitate with AgNO3 on heating but chloroform does...

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  8. A small amount of ethyl alcohol is usually added to chloroform bottles...

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  9. Organic halogen compounds used in industry as solvents are chlorides r...

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  10. What effect should the following resonance of vinyl chloride have on i...

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  11. Why is vinyl chloride less reactive than ethyl chloride ?

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  12. Why is chloroform not used as anaesthetic these days? What is the comm...

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  13. A hydrocarbon C(5)H(12) gives only one chlorination product. Identify ...

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  14. Predict the order of reactivity of the following compounds in S(N)1 re...

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  15. Allyl chloride is more reactive than n-propyl chloride towards unimo...

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  16. Write the various possible isomers of C(7)H(7)Cl containing benzene ri...

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  17. An alkyl halide with molecular formula C(4)H(9)Br is optically active....

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  18. Which out of the two : 2-cyclopentenol or 3-cyclopentenol has chiral c...

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  19. Allyl chloride is hydrolysed more readily than n-propyl chloride. Why ...

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  20. Write the structure of major monohalo product of the following reactio...

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