Home
Class 12
CHEMISTRY
Which compound in each of the following ...

Which compound in each of the following pairs will react faster in `S_(N)2` reaction with `.^(–)OH` ?
(i) `CH_(3)Br or CH_(3)I , (ii) (CH_(3))_(3)C Cl or CH_(3)Cl`

Text Solution

Verified by Experts

(a) `CH_(3)I` reacts faster than `CH_(3) Br` in `S_(N)2` reaction with `OH^(-)` because `I^(-)` ion is a better leaving group than `Br^(-)` ion
(b) `CH_(3)CI` is more reactive than `(CH_(3))_(3)C CI` because of steric hindrante in case of `(CH_(3))_(3)C CI`.
Promotional Banner

Topper's Solved these Questions

  • HALOALKANES AND HALOARENES

    MODERN PUBLICATION|Exercise NCERT examplar Problems (Multiple Choice Questions (Type-I))|31 Videos
  • HALOALKANES AND HALOARENES

    MODERN PUBLICATION|Exercise NCERT examplar Problems (Multiple Choice Questions (Type-II))|12 Videos
  • HALOALKANES AND HALOARENES

    MODERN PUBLICATION|Exercise NCERT Textbooks Exercises|1 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    MODERN PUBLICATION|Exercise COMPETION FILE (Integer Type Numerical Value Type Questions)|5 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|5 Videos

Similar Questions

Explore conceptually related problems

Which compound in each of the following pairs will react faster in S_(N)2 reaction with -OH ? Why? (i) CH_(3)Br or CH_(3)I (ii) (CH_(3))_(3)C Cl or CH_(3)Cl

Which compound in each of the following paris will react faster in SN^(2) reaction with HO^(o-) ? a. CH_(3)Br or CH_(3)I b. (CH_(3))_(3)CCl or CH_(3)Cl c. CH_(2) = CHBr or CH_(2) = CH - CH_(2)Br

Which compound in the following pairs will react faster in S_N^(2) reaction? (a). CH_(3)Br or CH_(3)I (b). (CH_(3))_(3)C Cl or CH_(3)Cl

(a) Draw the structures of major monohola prodcuts in each of the following reactions : 3 (i) (b) Which halogen compound in each following pairs will react faster in S_(N)2 reaction (i) CH_(3)Br or CH_(3)I (ii) CH_(3)C-CI or CH_(3)-CI

MODERN PUBLICATION-HALOALKANES AND HALOARENES-NCERT Textbooks Exercise
  1. Write the structures of the following organic halogen compounds. (i)...

    Text Solution

    |

  2. Which one of the following has the highest dipole moment? (i) CH(2)C...

    Text Solution

    |

  3. A hydrocarbon C(5)H(10) does not react with chlorine in dark but gives...

    Text Solution

    |

  4. Write the isomers of the compound having formula C(4)H(9)Br.

    Text Solution

    |

  5. Write the equations for the preparation of 1-iodobutane from (i) 1-b...

    Text Solution

    |

  6. What are ambident nucleophiles? Explain with an example.

    Text Solution

    |

  7. Which compound in each of the following pairs will react faster in S(N...

    Text Solution

    |

  8. Predict all the alkenes that would be formed by dehydrohalogenation of...

    Text Solution

    |

  9. आप निम्नलिखित परिवर्तन कैसे करेंगे ? (i) Ethanol to but-1-yne (ii)...

    Text Solution

    |

  10. Explain why (i) the dipole moment of chlorobenzene is lower than tha...

    Text Solution

    |

  11. Give the uses of freon 12, DDT, carbon tetrachloride and iodoform.

    Text Solution

    |

  12. Write the structure of the major organic product in each of the follow...

    Text Solution

    |

  13. Write the mechanism of the following reaction: nBuBr + KCN overset(E...

    Text Solution

    |

  14. Arrange the compounds of each set in order of reactivity towards S(N)2...

    Text Solution

    |

  15. Out of C(6)H(5)CH(2)Cl and C(6)H(5)CHClC(6)H(5), which is more easily ...

    Text Solution

    |

  16. p-Dichlorobenzene has higher m.p. and solubility than those of -and m-...

    Text Solution

    |

  17. How the following conversions can be carried out? (i) Propene to pro...

    Text Solution

    |

  18. The treatment of alkyl chlorides with aqueous KOH leads to the formati...

    Text Solution

    |

  19. Primary alkyl halide C(4)H(9)Br (a) reacted with alcoholic KOH to give...

    Text Solution

    |

  20. What happens when (i) n-butyl chloride is treated with alcoholic KOH...

    Text Solution

    |