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The reaction : RX + 2Na + RX overset("...

The reaction :
`RX + 2Na + RX overset("Dry ether")to R-R + 2NaX` is called :

A

Sandmeyer's reaction

B

Fittig reaction

C

Wurtz reaction

D

Williamson's synthesis.

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The correct Answer is:
The reaction given in the question is: \[ \text{RX} + 2\text{Na} \overset{\text{Dry ether}}{\rightarrow} \text{R-R} + 2\text{NaX} \] This reaction involves the coupling of two alkyl halides (RX) in the presence of sodium (Na) and a dry ether solvent, resulting in the formation of a hydrocarbon (R-R) and sodium halide (NaX). ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in the reaction are alkyl halides (RX) and sodium (Na). - The alkyl halide (RX) contains a carbon chain (R) bonded to a halogen (X). **Hint**: Look for the components involved in the reaction, which are alkyl halides and sodium. 2. **Understand the Role of Dry Ether**: - Dry ether acts as a solvent in this reaction. It is important because it helps in dissolving the reactants and facilitates the reaction between sodium and the alkyl halides. **Hint**: Consider the importance of the solvent in facilitating the reaction. 3. **Reaction Mechanism**: - Sodium donates electrons to the alkyl halide, leading to the formation of a radical or anions. - This results in the coupling of two alkyl groups (R) to form a new hydrocarbon (R-R). **Hint**: Think about how sodium interacts with the alkyl halide to form radicals or anions. 4. **Product Formation**: - The products of the reaction are a new alkane (R-R) and sodium halide (NaX). - The formation of R-R indicates that two alkyl groups have combined. **Hint**: Identify the products formed from the reactants and how they relate to the original compounds. 5. **Naming the Reaction**: - This reaction is known as the **Wurtz Reaction** (often misspelled as "Wood Reaction"). - It is specifically used for the coupling of alkyl halides to form higher alkanes. **Hint**: Recall the specific name associated with the reaction involving the coupling of alkyl halides. ### Final Answer: The reaction is called the **Wurtz Reaction**.
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Wurtz reaction involves the comdensation of two molecules of alkyl halides in the presence of sodium and dry ether R-X+2Na+R-Xoverset("dry ether")toR-R+2NaX In this reaction small amount of alkene is also formed as by product. CH_(3)CH_(2)Br+CH_(3)CH_(2)Broverset("Na/dry ether")toCH_(3)-CH_(2)-CH_(2)-CH_(3)+underset("By-product")ubrace(CH_(2)=CH_(2)+CH_(3)-CH_(3)) Tertiary alkyl halides do not give wurtz reaction. Frankland reaction is similar but has certain advantages over wurtz reaction. it is useful in the synthesis of symmetrical alkanes. frankland reaction is shown by primary, Secondary as well as tertiary alkyl halide. Q. A mixture of ethyl iodide and methyl iodide is subjected to wurtz reaction. the product that will not formed is

MODERN PUBLICATION-HALOALKANES AND HALOARENES-REVISION EXERCISE (Objective Questions) (Multiple choice questions)
  1. The IUPAC name of (CH(3))(3)C Cl is

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  2. Which of the following is not a chiral ?

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  3. The reaction : RX + 2Na + RX overset("Dry ether")to R-R + 2NaX is ca...

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  4. In S(N)1 reaction, the order of reactivity of halides is

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  5. C—X bond is strongest in

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  6. Reactivity order of halides of dehydrohalogenation is

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  7. Which one of the following gives only one monochloro derivative?

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  8. DDT is prepared by condensing chlorobenzene with

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  9. C(2)H(5)Cl on heating with alcoholic KOH will produce

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  10. Alkyl halides are less soluble in water because

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  11. Among the following, which one is chlorine containing insecticide?

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  12. The boiling points of haloalkanes follow the order:

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  13. Which of the following has highest dipole moment:

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  14. Which of the following is not a polyhalogen compound?

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  15. The ease of dehydrohalogenation of alkyl halide with alcoholic KOH is-

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  16. Alkyl halides are prepared from alcohol by treating with:

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  17. The organic chloro compound, which shows complete stereochemical inver...

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  18. Which of the following reaction is most suitable for the preparation o...

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  19. The reaction is:

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  20. In the given alkyl halides which one has minimum boiling point?

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