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The reaction : RX + 2Na + RX overset("...

The reaction :
`RX + 2Na + RX overset("Dry ether")to R-R + 2NaX` is called :

A

Sandmeyer's reaction

B

Fittig reaction

C

Wurtz reaction

D

Williamson's synthesis.

Text Solution

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The correct Answer is:
The reaction given in the question is: \[ \text{RX} + 2\text{Na} \overset{\text{Dry ether}}{\rightarrow} \text{R-R} + 2\text{NaX} \] This reaction involves the coupling of two alkyl halides (RX) in the presence of sodium (Na) and a dry ether solvent, resulting in the formation of a hydrocarbon (R-R) and sodium halide (NaX). ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in the reaction are alkyl halides (RX) and sodium (Na). - The alkyl halide (RX) contains a carbon chain (R) bonded to a halogen (X). **Hint**: Look for the components involved in the reaction, which are alkyl halides and sodium. 2. **Understand the Role of Dry Ether**: - Dry ether acts as a solvent in this reaction. It is important because it helps in dissolving the reactants and facilitates the reaction between sodium and the alkyl halides. **Hint**: Consider the importance of the solvent in facilitating the reaction. 3. **Reaction Mechanism**: - Sodium donates electrons to the alkyl halide, leading to the formation of a radical or anions. - This results in the coupling of two alkyl groups (R) to form a new hydrocarbon (R-R). **Hint**: Think about how sodium interacts with the alkyl halide to form radicals or anions. 4. **Product Formation**: - The products of the reaction are a new alkane (R-R) and sodium halide (NaX). - The formation of R-R indicates that two alkyl groups have combined. **Hint**: Identify the products formed from the reactants and how they relate to the original compounds. 5. **Naming the Reaction**: - This reaction is known as the **Wurtz Reaction** (often misspelled as "Wood Reaction"). - It is specifically used for the coupling of alkyl halides to form higher alkanes. **Hint**: Recall the specific name associated with the reaction involving the coupling of alkyl halides. ### Final Answer: The reaction is called the **Wurtz Reaction**.
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Wurtz reaction involves the comdensation of two molecules of alkyl halides in the presence of sodium and dry ether R-X+2Na+R-Xoverset("dry ether")toR-R+2NaX In this reaction small amount of alkene is also formed as by product. CH_(3)CH_(2)Br+CH_(3)CH_(2)Broverset("Na/dry ether")toCH_(3)-CH_(2)-CH_(2)-CH_(3)+underset("By-product")ubrace(CH_(2)=CH_(2)+CH_(3)-CH_(3)) Tertiary alkyl halides do not give wurtz reaction. Frankland reaction is similar but has certain advantages over wurtz reaction. it is useful in the synthesis of symmetrical alkanes. frankland reaction is shown by primary, Secondary as well as tertiary alkyl halide. Q. Which among the followng compound will give wurtz reaction with good yield ?

Wurtz reaction involves the comdensation of two molecules of alkyl halides in the presence of sodium and dry ether R-X+2Na+R-Xoverset("dry ether")toR-R+2NaX In this reaction small amount of alkene is also formed as by product. CH_(3)CH_(2)Br+CH_(3)CH_(2)Broverset("Na/dry ether")toCH_(3)-CH_(2)-CH_(2)-CH_(3)+underset("By-product")ubrace(CH_(2)=CH_(2)+CH_(3)-CH_(3)) Tertiary alkyl halides do not give wurtz reaction. Frankland reaction is similar but has certain advantages over wurtz reaction. it is useful in the synthesis of symmetrical alkanes. frankland reaction is shown by primary, Secondary as well as tertiary alkyl halide. Q. A mixture of ethyl iodide and methyl iodide is subjected to wurtz reaction. the product that will not formed is

Knowledge Check

  • The reaction 2R-Z+2Na overset("dry ether") to R-R+2NaX is an example of

    A
    Williamson'ssynthesis
    B
    Wurtz synthesis
    C
    Hoffman's synthsis
    D
    Cannizaros's reaction
  • The reaction , RCl + NaI overset(" Dry acetone")to R - I + NaCl is known as

    A
    Wurtz reaction
    B
    Fitting reaction
    C
    Wurtz-Fitting reaction
    D
    Finkelstein's reaction .
  • The 2 R - X + 2 Na overset("ether")(to) R - R + 2 Na X is an example of

    A
    Kolbe's reaction
    B
    Friedel- Crafts reaction
    C
    Wurtz reaction
    D
    Cannizzaro reaction .
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    Wurtz reaction involes the condensation of two molecules of alkyl halides in the presence of sodium and dry ether . R-X+2Na+X-Roverset("dry Ether")to R-R+2NaX in this reaction small amount of alkena is also formed as byproduct. CH_(3)CH_(2)+CH_(3)CH_(2)Broverset( "Na/dry Ether ") to CH_(3) -CH_(2)-CH_(2)-CH_(3) +H_(2)C= CH_(2) +underset("byproducts")ubrace(CH_(3)-CH_(3)) Tertiary alkyl halides do not give Wurtz reactio .Frankland reaction is similar but has certain advantages over Wurtz reaction it is useful in the synthesis of symmetrical alkanes Franlkans reaction is shown by primary , secondary as well as tertiary alkyl haidle. A mixture of ethyl iodine and methyl iodine is subjected to the Wurtz reaction ,the products formed are :

    Wurtz reaction involes the condensation of two molecules of alkyl halides in the presence of sodium and dry ether . R-X+2Na+X-Roverset("dry Ether")to R-R+2NaX in this reaction small amount of alkena is also formed as byproduct. CH_(3)CH_(2)+CH_(3)CH_(2)Broverset( "Na/dry Ether ") to CH_(3) -CH_(2)-CH_(2)-CH_(3) +H_(2)C= CH_(2) +underset("byproducts")ubrace(CH_(3)-CH_(3)) Tertiary alkyl halides do not give Wurtz reactio .Frankland reaction is similar but has certain advantages over Wurtz reaction it is useful in the synthesis of symmetrical alkanes Franlkans reaction is shown by primary , secondary as well as tertiary alkyl haidle. which among the following compounts will give Wurtz reaction ?

    Wurtz reaction involes the condensation of two molecules of alkyl halides in the presence of sodium and dry ether . R-X+2Na+X-Roverset("dry Ether")to R-R+2NaX in this reaction small amount of alkena is also formed as byproduct. CH_(3)CH_(2)+CH_(3)CH_(2)Broverset( "Na/dry Ether ") to CH_(3) -CH_(2)-CH_(2)-CH_(3) +H_(2)C= CH_(2) +underset("byproducts")ubrace(CH_(3)-CH_(3)) Tertiary alkyl halides do not give Wurtz reactio .Frankland reaction is similar but has certain advantages over Wurtz reaction it is useful in the synthesis of symmetrical alkanes Franlkans reaction is shown by primary , secondary as well as tertiary alkyl haidle. which of the following alkanes is not obtained from Wurtz reaction ?

    Wurtz reaction involes the condensation of two molecules of alkyl halides in the presence of sodium and dry ether . R-X+2Na+X-Roverset("dry Ether")to R-R+2NaX in this reaction small amount of alkena is also formed as byproduct. CH_(3)CH_(2)+CH_(3)CH_(2)Broverset( "Na/dry Ether ") to CH_(3) -CH_(2)-CH_(2)-CH_(3) +H_(2)C= CH_(2) +underset("byproducts")ubrace(CH_(3)-CH_(3)) Tertiary alkyl halides do not give Wurtz reactio .Frankland reaction is similar but has certain advantages over Wurtz reaction it is useful in the synthesis of symmetrical alkanes Franlkans reaction is shown by primary , secondary as well as tertiary alkyl haidle. which of the following compounds cannot be prepared by Wurtz reaction ?

    Wurtz reaction involes the condensation of two molecules of alkyl halides in the presence of sodium and dry ether . R-X+2Na+X-Roverset("dry Ether")to R-R+2NaX in this reaction small amount of alkena is also formed as byproduct. CH_(3)CH_(2)+CH_(3)CH_(2)Broverset( "Na/dry Ether ") to CH_(3) -CH_(2)-CH_(2)-CH_(3) +H_(2)C= CH_(2) +underset("byproducts")ubrace(CH_(3)-CH_(3)) Tertiary alkyl halides do not give Wurtz reactio .Frankland reaction is similar but has certain advantages over Wurtz reaction it is useful in the synthesis of symmetrical alkanes Franlkans reaction is shown by primary , secondary as well as tertiary alkyl haidle. Disproritionation takes place in :