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C(2)H(5)Cl on heating with alcoholic KOH...

`C_(2)H_(5)Cl` on heating with alcoholic KOH will produce

A

`C_(2)H_(5)OH`

B

`C_(2)H_(4)`

C

`C_(2)H_(2)`

D

`C_(2)H_(6)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of C₂H₅Cl (ethyl chloride) when heated with alcoholic KOH, we will follow these steps: ### Step 1: Identify the Reactants The reactant in this case is C₂H₅Cl (ethyl chloride) and the reagent is alcoholic KOH (potassium hydroxide in alcohol). **Hint:** Alcoholic KOH is a strong base that promotes elimination reactions rather than substitution. ### Step 2: Understand the Reaction Type When C₂H₅Cl is heated with alcoholic KOH, it undergoes an elimination reaction (dehydrohalogenation) rather than a substitution reaction. This is because the alcoholic medium favors the formation of alkenes. **Hint:** Look for the formation of a double bond in the product when a hydrogen halide is eliminated. ### Step 3: Determine the Elimination Mechanism In this reaction, KOH will abstract a hydrogen atom from the β-carbon (the carbon adjacent to the one bonded to Cl), and the Cl atom will be eliminated as a chloride ion (Cl⁻). This results in the formation of an alkene. **Hint:** Identify the β-hydrogen that will be removed to form the double bond. ### Step 4: Write the Reaction The elimination of HCl from C₂H₅Cl leads to the formation of ethylene (C₂H₄). The reaction can be summarized as follows: \[ \text{C}_2\text{H}_5\text{Cl} + \text{KOH (alc)} \rightarrow \text{C}_2\text{H}_4 + \text{KCl} + \text{H}_2\text{O} \] **Hint:** Remember to balance the equation and include all products formed. ### Step 5: Conclusion Thus, when C₂H₅Cl is heated with alcoholic KOH, the product formed is C₂H₄ (ethylene). **Final Answer:** C₂H₄ (ethylene) is produced. ---
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MODERN PUBLICATION-HALOALKANES AND HALOARENES-REVISION EXERCISE (Objective Questions) (Multiple choice questions)
  1. Which one of the following gives only one monochloro derivative?

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  2. DDT is prepared by condensing chlorobenzene with

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  3. C(2)H(5)Cl on heating with alcoholic KOH will produce

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  4. Alkyl halides are less soluble in water because

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  5. Among the following, which one is chlorine containing insecticide?

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  6. The boiling points of haloalkanes follow the order:

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  7. Which of the following has highest dipole moment:

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  8. Which of the following is not a polyhalogen compound?

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  9. The ease of dehydrohalogenation of alkyl halide with alcoholic KOH is-

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  10. Alkyl halides are prepared from alcohol by treating with:

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  11. The organic chloro compound, which shows complete stereochemical inver...

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  12. Which of the following reaction is most suitable for the preparation o...

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  13. The reaction is:

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  14. In the given alkyl halides which one has minimum boiling point?

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  15. S(N)2 reaction will be fastest in:

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  16. For the compounds, CH(3)Cl, CH(3)I, CH(3)Br and which of the followin...

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  17. Which of the following organic compounds are formed by Wurtz reaction?

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  18. In the preparation of alkyl halide from alcohol which of the following...

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  19. Complete the following reaction

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  20. Select the correct answer

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