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(a) How will you differentiate between S...

(a) How will you differentiate between `S_(N)1` and `S_(N)2` reactions?
(b) Why does the treatment of alkyl chloride with silver nitrate form nitroalkane and with potassium nitrite form alkyl nitrite?

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How would you differentiate between S_(N)1 and S_(N)2 mechanisms of substitution reactions? Give one example of each.

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Vinyl chloride does not give S_(N) reaction but alkyl chloride gives. Explain.