Home
Class 12
CHEMISTRY
The major product in the reaction is C...

The major product in the reaction is
`CH_(3)-underset(CH_(3))underset(|)CH-CH_(2)Br underset(CH_(3)OH)overset(CH_(3)O^(-))to`

A

`CH_(3)-underset(OCH_(3))underset(|)CH-CH_(2)CH_(3)`

B

`CH_(3)-underset(CH_(3))underset(|)C=CH_(2)`

C

`CH_(3)-underset(CH_(3))underset(|)CHCH_(2)OCH_(3)`

D

`CH_(3)-underset(OCH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the major product of the reaction involving `CH₃-CH(CH₃)-CH₂Br` with `CH₃OH` and `CH₃O⁻`, we will analyze the reaction step by step. ### Step 1: Identify the Reactants The reactants are: - `CH₃-CH(CH₃)-CH₂Br` (which is a haloalkane) - `CH₃OH` (methanol) - `CH₃O⁻` (methoxide ion, which acts as a base) ### Step 2: Determine the Role of the Base In this reaction, `CH₃O⁻` acts as a base. Bases can either participate in nucleophilic substitution reactions or elimination reactions. Given that we have a haloalkane and a strong base, we can expect an elimination reaction (E2 mechanism) to occur. ### Step 3: Identify the Elimination Mechanism In an E2 elimination, the base abstracts a proton (H) from a β-carbon (the carbon adjacent to the carbon bearing the leaving group, Br in this case) while the leaving group (Br) departs simultaneously. ### Step 4: Identify the β-Hydrogens The structure `CH₃-CH(CH₃)-CH₂Br` has the following β-hydrogens: - The hydrogen on the `CH₂` group (the carbon attached to Br) is a β-hydrogen. - The hydrogen on the `CH` group (the carbon attached to the first `CH₃`) is also a β-hydrogen. ### Step 5: Choose the β-Hydrogen to Abstract The base `CH₃O⁻` will abstract one of the β-hydrogens. In this case, it will abstract the hydrogen from the `CH₂` group because this leads to the formation of a more stable alkene product. ### Step 6: Elimination of the Leaving Group As the base abstracts the β-hydrogen, the Br atom leaves, resulting in the formation of a double bond between the two carbons involved in the elimination. ### Step 7: Draw the Major Product After the elimination, the structure will look like this: - The double bond will form between the `CH` and `CH₂` groups. - The product will be `CH₃-CH=CH₂` (propene). ### Final Product The major product of the reaction is: `CH₃-CH=CH₂` (propene).

To determine the major product of the reaction involving `CH₃-CH(CH₃)-CH₂Br` with `CH₃OH` and `CH₃O⁻`, we will analyze the reaction step by step. ### Step 1: Identify the Reactants The reactants are: - `CH₃-CH(CH₃)-CH₂Br` (which is a haloalkane) - `CH₃OH` (methanol) - `CH₃O⁻` (methoxide ion, which acts as a base) ...
Promotional Banner

Topper's Solved these Questions

  • HALOALKANES AND HALOARENES

    MODERN PUBLICATION|Exercise B. MULTIPLE CHOICE QUESTIONS (from competitive Examinations)|63 Videos
  • HALOALKANES AND HALOARENES

    MODERN PUBLICATION|Exercise C. MULTIPLE CHOICE QUESTIONS (with more than one correct answers)|10 Videos
  • HALOALKANES AND HALOARENES

    MODERN PUBLICATION|Exercise HIGHER ORDER THINKING SKILLS|13 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    MODERN PUBLICATION|Exercise COMPETION FILE (Integer Type Numerical Value Type Questions)|5 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|5 Videos

Similar Questions

Explore conceptually related problems

The major product formed in the reaction is: CH_(3)-underset(H)underset(|)overset(CH_(3))overset(|)(C)-CH_(2)Brunderset(CH_(3)OH)overset(CH_(3)O^(Ө))to

CH_(3)-underset(CH_(3))underset(|)(CH)-CH=CH-CH_(2)-overset(O)overset(||)(C)-OH

The major product formed in the reaction CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C )-CH_(2)underset(..)(ddotC)l:overset(Ag^(+))underset(H_(2)O)(rarr) is

The major product formed in the following reaction is : CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-underset(OH)underset(|)CH-CH_(3)underset("a few drops")overset("conc" H_(2)SO_(4))rarr Major product

The product formed in the reaction CH_(3)-underset(CH_(3))underset(|)C=CH_(2)+CH_(3)-overset(CH_(3))overset(|)CH-CH_(3)underset(0-10^(@)c)overset(HF)rarr is

The major product formed in the following reaction is CH_3-underset(H)underset(|)overset(CH_3)overset(|)C-CH_2Brunderset(CH_3OH)overset(CH_3O^(-))to

The major product (A) formed in the following reaction is CH_(3) - overset( CH_3) overset(|) CH-CH_2 - underset(CH_(3))underset(|) overset(CH_(3)-CH_() -CH_(3) ) overset(|)N-overset( o+)CH_(2) -CH_(3) underset( Delta ) overset( OH^(-)) (A)

The major product of the following reaction is : CH_(3)underset(overset(|)(Br))(C)HCH_(2)underset(overset(|)(Br))(C)HCH_(2)CH_(3) underset("heat")overset(KOH, CH_(3)OH)(to)

MODERN PUBLICATION-HALOALKANES AND HALOARENES-A. MULTIPLE CHOICE QUESTIONS (with only one correct answer)
  1. In the following reaction: The major product obtained is

    Text Solution

    |

  2. In the adddition of HBr to propene in the absence of peroxides, the fi...

    Text Solution

    |

  3. The major product in the reaction is CH(3)-underset(CH(3))underset(|...

    Text Solution

    |

  4. In the reaction: underset("(Major)")(A) overset(C(2)H(5)OH)larr (CH(...

    Text Solution

    |

  5. The product of the reaction of alcoholic silver nitrite with ethyl bro...

    Text Solution

    |

  6. When ethyl iodide and n-propyl iodide are allowed to react with sodium...

    Text Solution

    |

  7. 1,3-Dibromopropane reacts with metallic zinc to form

    Text Solution

    |

  8. Identify the set of reagents/ reaction condition ‘X’ and ‘Y’ in the fo...

    Text Solution

    |

  9. Butanenitrile may be prepared by heating

    Text Solution

    |

  10. Which of the following is least reactive in a nucleophilic substitutio...

    Text Solution

    |

  11. The most reactive nucleophile among the following is

    Text Solution

    |

  12. In the reaction, the major product 'X' is

    Text Solution

    |

  13. Chlorobenzene can be obtained from benzene diazonium chloride by

    Text Solution

    |

  14. Which of the following is most reactive toward nucleophilic substituti...

    Text Solution

    |

  15. The reaction fo toluenec with Cl(2) in presence of FeCl(3) gives predi...

    Text Solution

    |

  16. Which of the following sequence of reaction (reagents) can be used for...

    Text Solution

    |

  17. The increasing order of hydrolysis of the following compounds is

    Text Solution

    |

  18. Arrange the following compounds in order of increasing dipole moment ....

    Text Solution

    |

  19. In the following sequence of reactions, B is C(6)H(6) underset(FeCl(...

    Text Solution

    |

  20. 2-Phenyl-2-chloropropane on treatment with alc. KOH gives mainly

    Text Solution

    |