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Fluorobenzene is prepared by treating be...

Fluorobenzene is prepared by treating benzene diazonium chloride with fluoroboric acid and heating the product obtained. This reaction is known as:

A

Schiemann reaction

B

Sandmeyer reaction

C

Gattermann reaction

D

Ullmann reaction.

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The correct Answer is:
To determine the name of the reaction in which fluorobenzene is prepared by treating benzene diazonium chloride with fluoroboric acid, we can break down the process step by step. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reaction begins with benzene diazonium chloride (C6H5N2Cl) and fluoroboric acid (HBF4). The diazonium salt is a key intermediate in many aromatic substitution reactions. 2. **Reaction Mechanism**: When benzene diazonium chloride is treated with fluoroboric acid, the HBF4 dissociates into H+ and BF4-. The BF4- ion acts as a source of fluoride ions. 3. **Substitution Reaction**: The fluoride ion (F-) from BF4- replaces the chloride ion (Cl-) in the diazonium salt. This is a nucleophilic substitution reaction where the nucleophile (F-) attacks the positively charged carbon of the diazonium group. 4. **Formation of Fluorobenzene**: After the substitution occurs, the product formed is fluorobenzene (C6H5F). During this process, nitrogen gas (N2) is released as a byproduct, and HCl is also formed. 5. **Name of the Reaction**: The overall reaction is known as the **Balz-Schiemann reaction**. This name is attributed to the chemists who first described this method of synthesizing aryl fluorides from diazonium salts. ### Final Answer: The reaction in which fluorobenzene is prepared by treating benzene diazonium chloride with fluoroboric acid is known as the **Balz-Schiemann reaction**.
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MODERN PUBLICATION-HALOALKANES AND HALOARENES-A. MULTIPLE CHOICE QUESTIONS (with only one correct answer)
  1. The most reactive nucleophile among the following is

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  2. In the reaction, the major product 'X' is

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  3. Chlorobenzene can be obtained from benzene diazonium chloride by

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  4. Which of the following is most reactive toward nucleophilic substituti...

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  5. The reaction fo toluenec with Cl(2) in presence of FeCl(3) gives predi...

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  6. Which of the following sequence of reaction (reagents) can be used for...

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  7. The increasing order of hydrolysis of the following compounds is

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  8. Arrange the following compounds in order of increasing dipole moment ....

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  9. In the following sequence of reactions, B is C(6)H(6) underset(FeCl(...

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  10. 2-Phenyl-2-chloropropane on treatment with alc. KOH gives mainly

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  11. The major product (Z) in the following reaction is :

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  12. Fluorobenzene is prepared by treating benzene diazonium chloride with ...

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  13. Chlorobenzene is prepared commercially by :

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  14. When chlorobenzene is treated with NH(3) in presence of Cu(2)O in xyle...

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  15. The structure of the major product formed in the reaction is

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  16. Which of the following will give yellow precipitateon shaking with an ...

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  17. Freon-12 is commonly used as

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  18. Which of the following is the correct structure of D.D.T.?

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  19. Benzene hexachloride (BHC) is used as :

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  20. what happens when chloroform is exposed to air in presenc of sunli...

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