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Methylamine in water reacts with ferric ...

Methylamine in water reacts with ferric chloride to precipitate ferric hydroxide. Explain.

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To explain why methylamine in water reacts with ferric chloride to precipitate ferric hydroxide, we can break down the process into several steps: ### Step 1: Understanding Methylamine in Water Methylamine (CH₃NH₂) is a weak base. When it is dissolved in water, it can accept a proton (H⁺) from water, leading to the formation of methylammonium ions (CH₃NH₃⁺) and hydroxide ions (OH⁻). **Reaction:** \[ \text{CH}_3\text{NH}_2 + \text{H}_2\text{O} \rightleftharpoons \text{CH}_3\text{NH}_3^+ + \text{OH}^- \] ...
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Account for the following: (i) pK_(b) of aniline is more than that of methylamine. (ii) Ethylamine is soluble in water whereas aniline is not. (iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide. (iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline. (v) Aniline does not undergo Friedel-Crafts reaction. (vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.

Phenols react with ferric chloride solution to give :

Bonding in ferric chloride is

MODERN PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN -CONCEPTUAL QUESTIONS
  1. Why is aniline soluble in aqueous HCl?

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  2. Why is it difficult to prepare pure amines by ammonolysis of alkyl hal...

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  3. Methylamine in water reacts with ferric chloride to precipitate ferric...

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  4. Electrophilic substitution in case of aromatic amines takes place more...

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  5. Although boron trifluoride adds on trimethylamine but it does not add ...

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  6. Why does silver chloride dissolve in methylamine solution ?

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  7. Why does the reactivity of NH(2) get reduced in acetanilide ?

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  8. Although trimethyl amine and n-propylamine have the same molecular mas...

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  9. Sulphanilic acid is soluble in dil. NaOH but not in dil. HCl. Explain.

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  10. Glycine exists as NH(3)""^(+)CH(2)COO^(-) , zwitter ion but anthranili...

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  11. Tertiary amines do not undergo acylation. Explain.

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  12. Arrange the following sets in order of their basic strength in aqueous...

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  13. (i) Name the main product when aniline is heated with alcoholic KOH an...

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  14. Why do amines act as nucleophiles?

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  15. Aniline does not undergo Friedel Crafts alkylation. Explain.

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  16. Although —NH(2) group is an ortho and para directing group, nitration ...

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  17. The presence of a base is needed in the ammonolysis of alkyl halides. ...

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  18. Why cannot be aromatic primary amines prepared by Gabriel pthalimide s...

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  19. Suggest a structural formula of a compound having molecular formula C(...

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  20. Why does methylamine has lower boiling point than methanol ?

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