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Arrange the following sets in order of t...

Arrange the following sets in order of their basic strength in aqueous solution :
(i) `NH_(3), C_(6)H_(5)NH_(2), CH_(3)NH_(2), (CH_(3))_(3)N, (CH_(3))_(2)NH`
(ii) Aniline, p-nitroaniline, p-methylaniline.

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To determine the order of basic strength of the given compounds in aqueous solution, we will analyze two sets of compounds separately. ### Part (i): Arrange `NH3`, `C6H5NH2`, `CH3NH2`, `(CH3)3N`, `(CH3)2NH` in order of their basic strength. 1. **Identify the Types of Amines**: - `NH3` is ammonia. - `C6H5NH2` is aniline (aromatic amine). - `CH3NH2` is methylamine (aliphatic amine). ...
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MODERN PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN -CONCEPTUAL QUESTIONS
  1. Although boron trifluoride adds on trimethylamine but it does not add ...

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  2. Why does silver chloride dissolve in methylamine solution ?

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  3. Why does the reactivity of NH(2) get reduced in acetanilide ?

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  4. Although trimethyl amine and n-propylamine have the same molecular mas...

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  5. Sulphanilic acid is soluble in dil. NaOH but not in dil. HCl. Explain.

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  6. Glycine exists as NH(3)""^(+)CH(2)COO^(-) , zwitter ion but anthranili...

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  7. Tertiary amines do not undergo acylation. Explain.

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  8. Arrange the following sets in order of their basic strength in aqueous...

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  9. (i) Name the main product when aniline is heated with alcoholic KOH an...

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  10. Why do amines act as nucleophiles?

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  11. Aniline does not undergo Friedel Crafts alkylation. Explain.

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  12. Although —NH(2) group is an ortho and para directing group, nitration ...

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  13. The presence of a base is needed in the ammonolysis of alkyl halides. ...

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  14. Why cannot be aromatic primary amines prepared by Gabriel pthalimide s...

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  15. Suggest a structural formula of a compound having molecular formula C(...

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  16. Why does methylamine has lower boiling point than methanol ?

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  17. Identify A, B, C and D in the following conversions: A underset(0-5^...

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  18. Arrange the following compounds in the decreasing order of basicity :

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  19. Name the following reactions: (i) C(6)H(5)N(2)""^(+)Cl^(-) overset(C...

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  20. Arrange the following in the increasing order of their pK(b) values. ...

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