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Arrange the following in the increasing ...

Arrange the following in the increasing order of their `pK_(b)` values.
`C_(6)H_(5)NH_(2), C_(2)H_(5)NH_(2), C_(6)H_(5)NHCH_(3)`

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To solve the problem of arranging the compounds \( C_6H_5NH_2 \) (aniline), \( C_2H_5NH_2 \) (ethylamine), and \( C_6H_5NHCH_3 \) (N-methyl aniline) in increasing order of their \( pK_b \) values, we need to analyze the basicity of each compound. The \( pK_b \) value is inversely related to the basic strength; that is, the stronger the base, the lower the \( pK_b \) value. ### Step-by-Step Solution: 1. **Identify the Compounds**: - \( C_6H_5NH_2 \) is aniline. - \( C_2H_5NH_2 \) is ethylamine. - \( C_6H_5NHCH_3 \) is N-methyl aniline. ...
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Arrange the following: (i) In decreasing order of the pK_(b) values: C_(2)H_(5)NH_(2),C_(6)H_(5)NHCH_(3),(C_(2)H_(5))_(2)NHandC_(6)H_(5)NH_(2) (ii) In increasing order of basic strength: C_(6)H_(5)NH_(2),C_(6)H_(5)N(CH_(3))_(2),(C_(2)H_(5))_(2)NH andCH_(3)NH_(2) (iii) In increasing order of basic strength: (a) Aniline, p-nitroaniline and p-toluidine (b) C_(6)H_(5)NH_(2),C_(6)H_(5)NHCH_(3),C_(6)H_(5)CH_(2)NH_(2) (iv) In decreasing order of basic strength in gas phase: C_(2)H_(5)NH_(2),(C_(2)H_(5))_(2)NH,(C_(2)H_(5))_(3)NandNH_(3) (v) In increasing order of boiling point: C_(2)H_(5)OH,(CH_(3))_(2)NH,C_(2)H_(5)NH_(2) (vi) In increasing order of solubility in water: C_(6)H_(5)NH_(2),(C_(2)H_(5))_(2)NH,C_(2)H_(5)NH_(2^.)

Arrange the following in decreasing order of their basic strength: C_(6)H_(5)NH_(2), C_(2)H_(5)NH_(2), (C_(2)H_(5))_(2)NH, NH_(3) in aqueous solution.

Arrange the following in decreasing order of their basic strength : C_(6)H_(5)NH_(2),C_(2)H_(5)NH_(2),(C_(2)H_(5))_(2)NH_(3)

MODERN PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN -CONCEPTUAL QUESTIONS
  1. Although boron trifluoride adds on trimethylamine but it does not add ...

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  2. Why does silver chloride dissolve in methylamine solution ?

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  3. Why does the reactivity of NH(2) get reduced in acetanilide ?

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  4. Although trimethyl amine and n-propylamine have the same molecular mas...

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  5. Sulphanilic acid is soluble in dil. NaOH but not in dil. HCl. Explain.

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  6. Glycine exists as NH(3)""^(+)CH(2)COO^(-) , zwitter ion but anthranili...

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  7. Tertiary amines do not undergo acylation. Explain.

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  8. Arrange the following sets in order of their basic strength in aqueous...

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  9. (i) Name the main product when aniline is heated with alcoholic KOH an...

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  10. Why do amines act as nucleophiles?

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  11. Aniline does not undergo Friedel Crafts alkylation. Explain.

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  12. Although —NH(2) group is an ortho and para directing group, nitration ...

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  13. The presence of a base is needed in the ammonolysis of alkyl halides. ...

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  14. Why cannot be aromatic primary amines prepared by Gabriel pthalimide s...

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  15. Suggest a structural formula of a compound having molecular formula C(...

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  16. Why does methylamine has lower boiling point than methanol ?

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  17. Identify A, B, C and D in the following conversions: A underset(0-5^...

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  18. Arrange the following compounds in the decreasing order of basicity :

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  19. Name the following reactions: (i) C(6)H(5)N(2)""^(+)Cl^(-) overset(C...

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  20. Arrange the following in the increasing order of their pK(b) values. ...

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