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Give the structures of A, B and C in the...

Give the structures of A, B and C in the following reactions
(i) `CH_(3)CH_(2)I overset(NaCN)(to) A underset("hydrolysis Partial")overset(OH^(-))(to) B overset(NaOH+Br_(2))to C`
(ii) `C_(6)H_(5)N_(2)Cl overset(CuCN)to A overset(H_(2)O // H^(+))(to) B underset(Delta)overset(NH_(3))(to) C`
(iii) `CH_(3)CH_(2)Br overset(KCN)to A overset(LiAlH_(4))to B underset(0^(@)C)overset(HNO_(2))to C` (iv) `C_(6)H_(5)NO_(2) overset(Fe//HCl)to A underset(273 K)overset(NaNO_(2)+HCl)to B underset(Delta)overset(H_(2)O // H^(+))to C`
(v) `CH_(3)COOH underset(Delta)overset(NH_(3))to A overset(NaOBr)to B overset(NaNO_(2)//HCl)to C`
(vi) `C_(6)H_(5)NO_(2) overset(Fe//HCl)to A underset(273 K)overset(HNO_(2))to B overset(C_(6)H_(5)OH)to C`

Text Solution

AI Generated Solution

Let's break down the reactions step by step to find the structures of A, B, and C for each reaction. ### (i) Reaction: `CH3CH2I overset(NaCN)(to) A underset("hydrolysis Partial")overset(OH^(-))(to) B overset(NaOH+Br2)to C` 1. **Starting Material**: `CH3CH2I` (ethyl iodide). 2. **Reaction with NaCN**: - The cyanide ion (CN⁻) acts as a nucleophile and performs a nucleophilic substitution on the ethyl iodide. - **Product A**: `CH3CH2CN` (propionitrile). ...
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Give the structures of A, B and C in the following reactions: (i) CH_(3)CH_(2)Ioverset(NaCN)rarrAunderset("Partial h ydrolysis")overset(OH^(-))rarrBoverset(NaOH+Br_(2))rarrC (ii) C_(6)H_(5)N_(2)Cloverset(CuCN)rarrAoverset(H_(2)"O"//H^(+))rarrBunderset(Delta)overset(NH_(3))rarrC (iii) CH_(3)CH_(2)Broverset(KCN)rarrAoverset(LiAlH_4)rarrBunderset(0^@C)overset(HNO_2)rarrC (iv) C_(6)H_(5)NO_2overset(Fe//HCl)rarrAoverset(NaNO_(2)+HCl)underset(273 K)rarrBoverset(H_(2)"O"//H^(+))underset(Delta)rarrC (v) CH_(3)COOHoverset(NH_(3))underset(Delta)rarrAoverset(NaOBr)rarrBoverset(NaNO_(2)//HCl)rarrC (vi) C_(6)H_(5)NO_(2)overset(Fe//HCl)rarrAunderset(273K)overset(HNO_(2))rarrBoverset(C_(6)H_(5)OH)rarrC

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