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An amine (A) C(3)H(9)N reacts with nitro...

An amine (A) `C_(3)H_(9)N` reacts with nitrous acid at 0 to `5^(@)C` to give an oily layer separated from reaction mixture. Write the structure of A and its reaction with
(i) acetyl chloride
(ii) methyl magnesium bromide.

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MODERN PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN -REVISION EXERCISES SHORT ANSWER QUESTIONS
  1. Explain the following: (i) Tertiary amines do not undergo acylation....

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  2. An amine (A) C(3)H(9)N reacts with nitrous acid at 0 to 5^(@)C to give...

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  3. (a) Why have primary amines higher boiling point than tertiary amines?...

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  4. In the following cases rearrange the compounds as directed: (i) In a...

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  5. Complete the following chemical equations (i) C(6)H(5)N(2)Cl+C(6)H...

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  6. (a) Explain why an alkylamine is more basic than ammonia? (b) How wo...

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  7. (a) Complete the following reaction: (b) Explain ethylamine is mo...

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  8. (a) Write chemical test, to distinguish between CH(3)NH(2) and (CH(3))...

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  9. Write chemical equations for the following conversions: (i) Nitroben...

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  10. (a) (i) Convert aniline to fluorobenzene. (ii) Write structural form...

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  11. (a) Complete the following reactions: (i) C(6)H(5)NH(2) + CHCl(3) +...

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  12. (a) Complete the following reaction: (b) Convert aniline into ben...

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  13. How will you achieve the synthesis of only 4-bromoaniline from aniline...

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  14. (a) Why have primary amines higher boiling points than tertiary amines...

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  15. Give one chemical test to distinguish between the following pairs of c...

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  16. Account for the following: (i) pK(b) of aniline is more than that of...

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  17. Give the structures of A, B and C in the following reactions: (i) C(...

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  18. Write Hinsberg's test to distinguish primary, secondary and tertiary a...

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  19. Write short notes on the following: (i) Carbylamine reaction (ii) ...

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  20. How will you canvert the following : (i) Nitrobenzene into aniline, ...

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