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Give reasons for the following (a) Ace...

Give reasons for the following
(a) Acetylation of aniline reduces its activation effect.
(b) `CH_(3)NH_(2)` is more basiic than `C_(6)H_(5)NH_(2)`.
(c) Although `-NH_(2)` is o/p directing group, yet aniline on nitration gives a significant amount of m-nitroaniline.

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Why does acylation of -NH_(2) of aniline reduces its activating effect?

PK_(b) of aniline is less / more than p-C_(6)H_(4)(NH_(2))NH_(2)

MODERN PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN -REVISION EXERCISES SHORT ANSWER QUESTIONS
  1. (a) Write the chemical equations of: (i) Coupling reaction (ii) Me...

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  2. Identify A, B, C and D in the following conversions: A underset(273-...

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  3. Write the structures of A, B and C in the following: (i) C(6)H(5)CON...

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  4. (a) What happens when aniline reacts with bromine water at room temper...

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  5. (a) Classify the following amines as primary, secondary and tertiary....

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  6. Identify the compounds X, Y and Z in the following reactions:

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  7. (a) Explain, with the help of chemical equations, how the following co...

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  8. (a) Name the test used to identify primary amines using CHCl(2) and et...

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  9. Write the structures of main products when benzene diazonium chloride ...

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  10. Write equations of the following reactions: (i) Acetylation of anili...

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  11. (a) Arrange the following compounds in an increasing order of basic st...

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  12. Give the chemical tests to distinguish between the following pairs of ...

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  13. Given the chemical tests to distinguish between the following pairs of...

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  14. Give the structures of the products A, B and C in the following reacti...

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  15. Complete the following reactions : (i) CH(3)CH(2)NH(2) + CHCl(2) + a...

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  16. Write the main products of the following reactions : (i) C(6)H(5)N(2...

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  17. Write the main products of the following reactions: (i) CH(3)CH(2)NH...

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  18. Write the structures of A, B and C in the following: (i) C(6)H(5)COO...

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  19. Give reasons for the following (a) Acetylation of aniline reduces it...

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  20. Write the structures of compounds A, B and Cin the following reactions...

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