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Diethylamine reacts with nitrous acid to...

Diethylamine reacts with nitrous acid to give

A

`(C_(2)H_(5)) _(2)NH^(+)NO_(2)""^(-)`

B

`(C_(2)H_(5)) _(2)N NO`

C

`C_(2)H_(5)OH`

D

`N_(2)` and alcohol.

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The correct Answer is:
To solve the problem of what diethylamine reacts with nitrous acid to give, we can follow these steps: ### Step 1: Understand the Reactants Diethylamine is an organic compound with the formula \( (C_2H_5)_2NH \). Nitrous acid is represented as \( HNO_2 \). ### Step 2: Reaction Mechanism When diethylamine reacts with nitrous acid, the nitrogen atom in diethylamine can be protonated by the nitrous acid, leading to the formation of a diazonium ion. The reaction can be summarized as follows: 1. **Protonation of Diethylamine**: The lone pair on the nitrogen of diethylamine accepts a proton from nitrous acid, forming a diethylammonium ion. \[ (C_2H_5)_2NH + HNO_2 \rightarrow (C_2H_5)_2NH_2^+ + NO_2^- \] 2. **Formation of Diazonium Ion**: The nitrous acid can then react with the diethylammonium ion, leading to the formation of a diazonium ion. \[ (C_2H_5)_2NH_2^+ + HNO_2 \rightarrow (C_2H_5)_2N^+ \equiv N + 2H_2O \] ### Step 3: Identify the Product The product of this reaction is diethyl diazonium ion, represented as \( (C_2H_5)_2N^+ \equiv N \). ### Step 4: Conclusion Thus, the reaction of diethylamine with nitrous acid results in the formation of diethyl diazonium ion. ### Final Answer The product formed when diethylamine reacts with nitrous acid is diethyl diazonium ion, represented as \( (C_2H_5)_2N^+ \equiv N \). ---

To solve the problem of what diethylamine reacts with nitrous acid to give, we can follow these steps: ### Step 1: Understand the Reactants Diethylamine is an organic compound with the formula \( (C_2H_5)_2NH \). Nitrous acid is represented as \( HNO_2 \). ### Step 2: Reaction Mechanism When diethylamine reacts with nitrous acid, the nitrogen atom in diethylamine can be protonated by the nitrous acid, leading to the formation of a diazonium ion. The reaction can be summarized as follows: ...
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MODERN PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN -Competition File (OBJECTIVE TYPE QUESTIONS) (MULTIPLE CHOICE QUESTIONS (M.C.Q)) (A)
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  2. Silver chloride is soluble in methylamine due to the formation of:

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  3. Diethylamine reacts with nitrous acid to give

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  4. Maximum pK(b) value is of

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  5. Reaction of acetamide with bromine and KOH gives

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  6. Hoffmann degradation of m-bromobenzamide gives

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  7. Which of the following is Hofmann mustard oil reaction?

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  8. On heating aniline with CS(2) in the presence of HgCl(2) the product i...

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  9. The reagents needed to convert is/are

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  10. A positive carbylamine test is given by:

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  11. In the reaction

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  12. The compound C5 H(13) N is optically active and reacts with HONO to gi...

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  13. In the reaction of p-chlorotoluene with KNH(2) is liguid NH(3) the maj...

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  14. p-chloroaniline and anilinium hydrochloride cannot be distinguished by

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  15. CH(3)CH(2)Cloverset(NaCN)rarrXoverset(Ni//H(2))rarrYunderset("anhydrid...

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  16. The reaction of chloroform with alcoholic KOH and p-toluidine forms:

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  17. In the following reaction, the product A is

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  18. Which of the following compounds will dissolve in an alkali solution a...

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  19. Secondary amines could be prepared by

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  20. In Balz-Schiemann reaction, benzene diazonium chloride reacts with

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