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Which of the following is Hofmann mustar...

Which of the following is Hofmann mustard oil reaction?

A

Reaction of aromatic amine with iodoform

B

Reaction of primary amine with `CHCl_(3)`

C

Reaction of primary amine with `CS_(2)` and `HgCl_(2)`

D

Reaction of secondary amine with nitrous acid.

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The correct Answer is:
C


This reaction is called Hoffmann mustard oil reaction.
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MODERN PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN -Competition File (OBJECTIVE TYPE QUESTIONS) (MULTIPLE CHOICE QUESTIONS (M.C.Q)) (A)
  1. Reaction of acetamide with bromine and KOH gives

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  2. Hoffmann degradation of m-bromobenzamide gives

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  3. Which of the following is Hofmann mustard oil reaction?

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  4. On heating aniline with CS(2) in the presence of HgCl(2) the product i...

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  5. The reagents needed to convert is/are

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  6. A positive carbylamine test is given by:

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  7. In the reaction

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  8. The compound C5 H(13) N is optically active and reacts with HONO to gi...

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  9. In the reaction of p-chlorotoluene with KNH(2) is liguid NH(3) the maj...

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  10. p-chloroaniline and anilinium hydrochloride cannot be distinguished by

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  11. CH(3)CH(2)Cloverset(NaCN)rarrXoverset(Ni//H(2))rarrYunderset("anhydrid...

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  12. The reaction of chloroform with alcoholic KOH and p-toluidine forms:

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  13. In the following reaction, the product A is

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  14. Which of the following compounds will dissolve in an alkali solution a...

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  15. Secondary amines could be prepared by

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  16. In Balz-Schiemann reaction, benzene diazonium chloride reacts with

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  17. The indicator methyl orange is prepared by coupling dia- zonium salt o...

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  18. Benzene diazonium chloride on reaction with phenol in weakly basic med...

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  19. Which of the following reaction represents Sandmeyer's reaction?

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  20. Aniline when diazotized in cold and then treated with dimethyl aniline...

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