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Acetamide is treated with the following ...

Acetamide is treated with the following reagents seprately.Which one of these would yield methyl amine?

A

Hot conc. `H_(2)SO_(4)`

B

`PCl_(5)`

C

`NaOH – Br_(2)`

D

Sodalime

Text Solution

Verified by Experts

The correct Answer is:
C
`CH_(3)-underset(O)underset(||)(C)-NH_(2) underset(Br_(2))overset(NaNO_(2))(to) CH_(3)NH_(2)`
This reaction is Hoffmann degradation reaction.
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MODERN PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN -Competition File (B) MULTIPLE CHOICE QUESTIONS
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  2. Nitrobenzene can be prepared from benzene by using a mixture of cone. ...

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  3. Acetamide is treated with the following reagents seprately.Which one o...

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  4. Aniline in a set of the following reactions yielded a coloured product...

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  5. Which of the following statements about primary amines is false ? .

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  6. Aniline is treated with NaNO(2) // HCl at 0^(@)C to give compound X wh...

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  7. What is the product obtained in the following reaction ?

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  8. Aniline is treated wi.th bromine water to give an organic compound X w...

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  9. Secondary amines could be prepared by

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  10. In the reaction:

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  11. Nitrobenzene on reaction with conc HNO(3)//H(2)SO(4) at 80-100^(@)C fo...

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  12. Which of the following will be most stable diazonium salt RN(2)^(+)Xba...

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  13. In the following reaction, the product (A)

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  14. The number of structure isomers possible from the molecular formula C(...

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  15. The following reaction : is known by the name:

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  16. Method by which aniline cannot be prepared is:

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  17. The electrolytic reduction of nitrobenzene in strongly acidic medium p...

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  18. Which one of the following amines cannot be prepared by Gabriel phtahl...

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  19. Which one of the following amines forms a non-acidcic and alkali insol...

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  20. Which one of the following -compounds does not react with nitrous acid...

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