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Explain the following reactions by givin...

Explain the following reactions by giving one example :
(i) Carbylamine reaction (ii) Sandmeyer's reaction
(iii) Balz-Schiemann reaction

Text Solution

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### Step-by-Step Text Solution #### (i) Carbylamine Reaction The Carbylamine reaction involves the reaction of primary amines with chloroform (CHCl₃) in the presence of a strong base such as potassium hydroxide (KOH). When a primary amine (RNH₂) is heated with chloroform and KOH, it produces isocyanide (also known as carbylamine) and potassium chloride (KCl) as a byproduct. **Example:** Consider the reaction of ethylamine (C₂H₅NH₂) with chloroform and KOH: 1. **Reactants:** Ethylamine (C₂H₅NH₂) + Chloroform (CHCl₃) + KOH ...
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Knowledge Check

  • In carbylamine reaction:

    A
    the nucleophilic is `RNH_(2)` and electrophilie is `C Cl_(2)`
    B
    the nucleophilic is primary amine and electrophile is `C Cl_(3)^(-)`
    C
    the nucleophilic is `C Cl_(3)^(-)` and the electrophile is primary amine
    D
    the attracting reagent is electrophile
  • The carbylamine reaction is

    A
    B
    C
    D
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