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Four sucessive members of the first two ...

Four sucessive members of the first two transition elements are listed below with their atomic numbers. Which one of them is expected to have highest third ionisation enthalpy ?

A

Vanadium (Z = 23)

B

Chromium (Z = 24)

C

Manganese (Z = 25)

D

Iron (Z = 26)

Text Solution

Verified by Experts

The correct Answer is:
C

For third ionisation energy, the last configuration are :
`V : 3d^(3) : Cr : 3d^(4) : Mn : 3d^(5) , Fe : 3d^(6)`
So Mn has stable configuration due to half filld d-subshell.
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MODERN PUBLICATION-CHEMISTRY OF D-AND F-BLOCK ELEMENTS-Multiple Choice Questions (Level-II)
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  2. The number of moles of KMnO(4) reduced by one mole of Kl in alkaline m...

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  3. Four sucessive members of the first two transition elements are listed...

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  4. The aqueous solution containing which one fo the following ions will b...

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  5. Copper sulphate dissolves in excess of KCN to give :

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  6. Which is not correct about the chemistry of 3d and 4f series elements ...

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  7. The approximate percentage of iron in mischmetal is :

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  8. To an acidic solution of anion a few drops of acidified KMnO(4) are ...

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  9. The electronic configuration of transition element "X", is +3, oxidati...

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  10. The magnetic nature of elements depends on the presence of unpaired el...

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  11. Which of the following is amphoteric oxide ? Mn(2)O(7), CrO(3), Cr...

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  12. Gadolinium belongs to 4f series. Its atomic number is 64. Which of the...

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  13. KMnO(4) acts as an oxidising agent in alkaline medium. When alkaline K...

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  14. Although Zirconium belongs to 4d transition series and Hafnium to 5d t...

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  15. Why is HCl not used to make the medium acidic in oxidation reactions ...

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  16. In a reaction K(2)MnO(4) is converted into KMnO(4) The change in the ...

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  17. The stable oxidation state of Ce (Z = 58) is

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  18. In the reaction : CrO(4)^(2-) + X to Cr(2)O(7)^(2-) X is

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  19. In which of the following pairs, the atomic size is almost the same ?

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  20. Which of the following statement is not correct ?

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