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Which of the following sets of quantam n...

Which of the following sets of quantam numbers represent electron in hydrozen atom

A

1,1,0 `+(1//2)`

B

1,0,0, `+(1//2)`

C

3,0,0 `-(1//2)`

D

4,2,1 `-(1//2)`

Text Solution

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The correct Answer is:
To determine which set of quantum numbers represents an electron in a hydrogen atom, we need to understand the quantum numbers and the electron configuration of hydrogen. ### Step-by-Step Solution: 1. **Identify the Electron Configuration of Hydrogen:** - Hydrogen has one electron, and its electron configuration is \(1s^1\). This means that the electron is in the first energy level (n=1) and in the s subshell. 2. **Determine the Quantum Numbers:** - The quantum numbers for an electron in a hydrogen atom can be defined as follows: - **Principal Quantum Number (n)**: This represents the energy level of the electron. For hydrogen, since it has one electron in the first shell, \(n = 1\). - **Azimuthal Quantum Number (l)**: This represents the subshell. For an s subshell, \(l = 0\). - **Magnetic Quantum Number (m)**: This represents the orientation of the orbital. For \(l = 0\), the only possible value for \(m\) is \(0\). - **Spin Quantum Number (s)**: This represents the spin of the electron. It can be either \(+\frac{1}{2}\) (spin up) or \(-\frac{1}{2}\) (spin down). 3. **Construct the Possible Sets of Quantum Numbers:** - Based on the above information, the quantum numbers for the electron in hydrogen can be: - For the first electron in the 1s orbital: - Set 1: \( (n=1, l=0, m=0, s=+\frac{1}{2}) \) - Set 2: \( (n=1, l=0, m=0, s=-\frac{1}{2}) \) 4. **Evaluate the Given Options:** - Now, we need to compare the possible sets with the given options: - Option 1: \( (1, 1, 0) \) - This is incorrect because \(l\) should be \(0\) for an s orbital. - Option 2: \( (1, 0, 0, +\frac{1}{2}) \) - This is correct as it corresponds to the first electron in the 1s orbital. - Option 3: \( (1, 0, 0, -\frac{1}{2}) \) - This is also a valid set for the second electron in the 1s orbital but is not listed as an option. 5. **Conclusion:** - The correct set of quantum numbers that represents an electron in a hydrogen atom is Option 2: \( (1, 0, 0, +\frac{1}{2}) \).
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