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Why does the reactivity of nitrogen diff...

Why does the reactivity of nitrogen differ from phosphorus ?

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Nitrogen has a unique ability to form `p pi - p pi ` multiple bonds with itself and with other elements having small size and high electronegativity (e.g. C, O). Therefore, it has triple bond between two nitrogen atoms (N = N) and is non-polar. Due to triple bond it has very high bond enthalpy (941.4 kJ) and therefore, it does not react with other elements under normal conditions and is very unreactive. On the other hand, phosphorus forms single bond (P-P) and is reactive in comparison to nitrogen.
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MBD -HARYANA BOARD-P BLOCK ELEMENTS-SHORT ANSWER TYPE QUESTIONS
  1. Discuss abnormal behaviour of nitrogen.

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  2. What is the basicity of H3PO4 ?

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  3. Why does the reactivity of nitrogen differ from phosphorus ?

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  4. Illustrate how copper metal can give different products on reaction wi...

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  5. What happens when copper reacts with (i) conc. HNO3 (ii) Dil. HNO3 ...

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  6. (i) HF is liquid while HCl is gas, why? (ii) Give the increasing o...

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  7. Arrange HCIO4, HCIO3, HCIO2 and HCIO in the increasing order of acidic...

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  8. Why is nitrogen inert while phosphorus is reactive ?

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  9. Why is nitrogen a gas while phosphorus is solid ?

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  10. (i) Explain O2 is gas and sulphur is solid. (ii) Give the reacti...

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  11. Why is dioxygen a gas but sulphur a solid ?

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  12. How is nitrogen prepared in the laboratory? Write the chemical equatio...

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  13. What inspired N. Bartlett for carrying out reaction between Xe and PtF...

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  14. Write balanced equations for the following: (a) NaCl is heated with ...

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  15. (a) Account for the following observations: (i) Hydrogen fluoride has ...

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  16. (a) SF6 is not easily hydrolysed. Explain. (b) Ozone is used for pur...

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  17. (a) Write one chemical reaction to show that conc. H2SO4 can be an o...

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  18. How is ozone estimated quantitatively?

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  19. Explain : (a) SF6 is known but SH6 is not known. Explain. (...

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  20. Give two examples to show the anomalous behaviour of fluorine.

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