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Why does the reactivity of nitrogen diff...

Why does the reactivity of nitrogen differ from phosphorus ?

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Nitrogen has a unique ability to form `p pi - p pi ` multiple bonds with itself and with other elements having small size and high electronegativity (e.g. C, O). Therefore, it has triple bond between two nitrogen atoms `(N -= N)` and is non-polar. Due to triple bond it has very high bond enthalpy (941.4 kJ) and therefore, it does not react with other elements under normal conditions and is very unreactive. On the other hand, phosphorus forms single bond (P - P) and is reactive in comparison to nitrogen.
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MBD -HARYANA BOARD-P BLOCK ELEMENTS-SHORT ANSWER TYPE QUESTIONS
  1. (a) Account for the following observations: (i) Hydrogen fluoride has ...

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  2. (a) SF6 is not easily hydrolysed. Explain. (b) Ozone is used for pur...

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  3. (a) Write one chemical reaction to show that conc. H2SO4 can be an o...

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  4. How is ozone estimated quantitatively?

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  5. Explain : (a) SF6 is known but SH6 is not known. Explain. (...

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  6. Give two examples to show the anomalous behaviour of fluorine.

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  7. How is nitrogen prepared in the laboratory? Write the chemical equatio...

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  8. Why does the reactivity of nitrogen differ from phosphorus ?

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  9. Explain why NH3 is basic while BiH3 is only feebly basic.

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  10. Why is dioxygen a gas but sulphur'a solid ?

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  11. Knowing the electron gain enthalpy values for O to O^(-) and O to O^...

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  12. Write two uses of ClO2

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  13. Why are halogens coloured ?

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  14. Write balanced equations for the following: (a) NaCl is heated with...

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  15. What is the reaction of conc. H2SO4 with (i) Sulphur (ii) Carbon ?

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  16. What is the shape of XeF4 molecule ?

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  17. (a) (CH3)3N is basic, but (CF3)3 N is not basic. Explain. (b) El...

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  18. What are interhalogen compounds ? Give examples.

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  19. Why are interhalogen compounds more reactive than halogens ?

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  20. Why does nitrogen show catenation properties less than phosphorus ?

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